If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
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For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
151882
Deuterium oxide
99.9 atom % D
Synonym(s):
Heavy water, Water-d2
About This Item
bio NMR: suitable
Recommended Products
isotopic purity
99.9 atom % D
Quality Level
form
liquid
technique(s)
NMR: suitable
bio NMR: suitable
bp
101.4 °C (lit.)
mp
3.8 °C (lit.)
storage temp.
room temp
SMILES string
[2H]O[2H]
InChI
1S/H2O/h1H2/i/hD2
InChI key
XLYOFNOQVPJJNP-ZSJDYOACSA-N
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Related Categories
General description
Application
- To prepare trifluoroacetic acid-d by reacting with trifluoroacetic anhydride.[4]
- As a deuteration agent for primary and secondary alcohols at the β-carbon position via H/D exchange reaction in the presence of ruthenium catalyst.[5]
- Along with hexamethyldisilane as a deuterium transfer reagent for alkynes to form (E)-1,2-dideuterioalkenes in the presence of a palladium complex.[6]
Recommended products
also commonly purchased with this product
Storage Class Code
12 - Non Combustible Liquids
WGK
nwg
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Articles
Use this reference table to find the coupling values and chemical shifts of our NMR (deuterated) solvents. Melting and boiling points, molecular weight, density, and CAS number are also listed.
Use this reference table to find the coupling values and chemical shifts of our NMR (deuterated) solvents. Melting and boiling points, molecular weight, density, and CAS number are also listed.
Use this reference table to find the coupling values and chemical shifts of our NMR (deuterated) solvents. Melting and boiling points, molecular weight, density, and CAS number are also listed.
Use this reference table to find the coupling values and chemical shifts of our NMR (deuterated) solvents. Melting and boiling points, molecular weight, density, and CAS number are also listed.
Related Content
NMR spectroscopy elucidates molecular structure and purity via nuclear spin states in a strong magnetic field.
NMR spectroscopy elucidates molecular structure and purity via nuclear spin states in a strong magnetic field.
NMR spectroscopy elucidates molecular structure and purity via nuclear spin states in a strong magnetic field.
NMR spectroscopy elucidates molecular structure and purity via nuclear spin states in a strong magnetic field.
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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Does this product (Cat. No 151882) contain propionic acid (C₃H₆O₂)?
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This product does not contain propionic acid. Deuterium preprarations that include propionic acid may be reviewed at the link below:
https://www.sigmaaldrich.com/search/deuterium-propionate?focus=products&page=1&perpage=30&sort=relevance&term=deuterium%20propionate&type=productHelpful?
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I don't have the ability to store Product 151882, Deuterium oxide, under nitrogen to prevent H2O uptake. Is there another way that I can work with D20 in order to preserve its purity?
1 answer-
You may be interested in our ampulized deuterium oxide products: 521965 (10x0.6mL), 441376 (10x0.75mL) or 269794 (10x1mL). These products are ideal for one time use applications, like as an NMR solvent, because there is decreased chance of water uptake during storage.
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What is the Department of Transportation shipping information for this product?
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Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
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How should I store Product 151882, Deuterium oxide, to preserve its purity?
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According to our MSDS, deuterium oxide is classified as hygroscopic and should be stored under an inert gas like nitrogen, to prevent hydrogenated water uptake.
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