132225
Troger′s Base
98%
Synonym(s):
2,8-Dimethyl-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine
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About This Item
Empirical Formula (Hill Notation):
C17H18N2
CAS Number:
Molecular Weight:
250.34
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
98%
form
powder
technique(s)
photometry: suitable
mp
133-136 °C (lit.)
SMILES string
Cc1ccc2[N@@H]3C[N@@H](Cc2c1)c4ccc(C)cc4C3
InChI
1S/C17H18N2/c1-12-3-5-16-14(7-12)9-18-11-19(16)10-15-8-13(2)4-6-17(15)18/h3-8H,9-11H2,1-2H3
InChI key
SXPSZIHEWFTLEQ-UHFFFAOYSA-N
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Xin Du et al.
Chemical communications (Cambridge, England), 46(6), 970-972 (2010-01-29)
An organic nanoporous polymer (BET surface area of 750 m(2) g(-1)) containing bicovalently-bonded Tröger's base as functional moieties in the network was synthesized, characterised, and further applied as a promising heterogeneous catalyst in the addition reaction of diethylzinc to aromatic
Junjie Ou et al.
Journal of biochemical and biophysical methods, 70(1), 71-76 (2006-09-19)
Two chiral compounds, Tröger's base and tetrahydropalmatine, were enantioseparated on the (5S, 11S)-(-)-Tröger's base and l-tetrahydropalmatine imprinted monolithic capillary columns with CEC, respectively. The monoliths were prepared by in situ thermal-initiated copolymerization of methacrylic acid (MAA) and ethylene dimethacrylate (EDMA).
Carlos A M Abella et al.
The Journal of organic chemistry, 72(11), 4048-4054 (2007-05-03)
Using direct infusion electrospray ionization mass and tandem mass spectrometric experiments [ESI-MS(/MS)], we have performed on-line monitoring of some reactions used to form Tröger's bases. Key intermediates, either as cationic species or as protonated forms of neutral species, have been
Shigeharu Katsuo et al.
Journal of chromatography. A, 1218(52), 9345-9352 (2011-11-29)
One of the modified simulated moving bed (SMB) processes, the intermittent SMB (I-SMB) process, has been recently analyzed theoretically [1] and its superior performance compared to the conventional SMB process has been demonstrated at a rather low total feed concentration
Y Coppel et al.
Journal of biomolecular structure & dynamics, 12(3), 637-653 (1994-12-01)
The two enantiomeric forms: 1R,5R (R) and 1S,5S (S) of the Troeger's base analog, 9,19-methano-9,10,19,20-tetrahydrodiacridino-[b,f]-[1,5]- diazocine which possess a C2 axis of symmetry, are susceptible to interact differently with DNA. This paper reports the results of molecular modelling calculations on
Chromatograms
application for HPLCapplication for HPLCapplication for HPLCActive Filters
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