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123358

Sigma-Aldrich

1-Chloro-2-methylpropene

98%

Synonym(s):

Isocrotyl chloride

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About This Item

Linear Formula:
(CH3)2C=CHCl
CAS Number:
513-37-1
Molecular Weight:
90.55
Beilstein:
1733843
EC Number:
208-158-4
MDL number:
MFCD00000924
UNSPSC Code:
12352100
PubChem Substance ID:
24847560
NACRES:
NA.22

Assay

98%

refractive index

n20/D 1.424 (lit.)

bp

68 °C (lit.)

density

0.92 g/mL at 25 °C (lit.)

SMILES string

C\C(C)=C\Cl

InChI

1S/C4H7Cl/c1-4(2)3-5/h3H,1-2H3

InChI key

KWISWUFGPUHDRY-UHFFFAOYSA-N

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General description

1-Chloro-2-methylpropene undergoes hydroboration to form an adduct, which on oxidation forms isobutyraldehyde.

Application

1-Chloro-2-methylpropene was used to study multiple infrared photon excitation of α-chloro olefins.

Signal Word

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 3 Dermal - Carc. 1B - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

30.2 °F - closed cup

Flash Point(C)

-1 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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R E Cannon et al.
Molecular carcinogenesis, 29(4), 229-235 (2001-02-15)
This work was initiated to determine the potential for the Tg.AC mouse model to identify chemical carcinogens by an oral route of administration. Tg.AC v-Ha-ras transgenic mice were exposed to dimethyvinyl chloride (DMVC; 1-chloro-2-methylpropene), a structural analog of the human
Formation of vinylidenecarbene intermediates in multiple infrared photon elimination reactions.
Reiser C and Steinfeld JI.
The Journal of Physical Chemistry, 84(6), 680-681 (1980)
Dimethylvinyl chloride.
Report on carcinogens : carcinogen profiles, 11, III110-III110 (2004-01-01)
P Srinivas et al.
Drug metabolism and disposition: the biological fate of chemicals, 16(3), 449-454 (1988-05-01)
Recent metabolism and disposition studies of 1-chloro-2-methylpropene (dimethylvinyl chloride) revealed cysteine and N-acetylcysteine conjugates of 3-chloro-2-methylpropenoic acid as the major metabolites. In the present studies we have investigated various steps in the metabolic pathway to determine which step was responsible
1-Chloro-2-methylpropene.
IARC monographs on the evaluation of carcinogenic risks to humans, 63, 315-324 (1995-01-01)
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