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95420

Sigma-Aldrich

Tungstic acid

≥98.0% (calcined substance, T), powder

Synonym(s):

Tungstic(VI) acid

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About This Item

Linear Formula:
H2WO4
CAS Number:
7783-03-1
Molecular Weight:
249.85
EC Number:
231-975-2
MDL number:
MFCD00011336
UNSPSC Code:
12352300
PubChem Substance ID:
57653679
NACRES:
NA.23

Assay

≥98.0% (calcined substance, T)

form

powder

impurities

≤0.2% insoluble matter in NaOH

loss

≤9.0% loss on ignition

density

5.5 g/mL at 25 °C (lit.)

SMILES string

O[W](O)(=O)=O

InChI

1S/2H2O.2O.W/h2*1H2;;;/q;;;;+2/p-2

InChI key

CMPGARWFYBADJI-UHFFFAOYSA-L

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General description

Tungstic acid may be prepared by either digesting tungstate of lime or by treating tungsten with hydrochloric acid. 1

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Thierry Barré et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 61(4), 551-557 (2005-01-15)
This study is focused on the composition and the evolution of tungstate ions solutions as a function of pH and increasing concentrations. The Raman analysis showed that, during the titration of the tungstate solutions, WO4(2-), HWO4- ions and probably W2O7(2-)
Multiple reversible protonation of polyoxoanion surfaces: direct observation of dynamic structural effects from proton transfer.
Xikui Fang et al.
Angewandte Chemie (International ed. in English), 46(21), 3877-3880 (2007-04-20)
Laura Barrio et al.
The journal of physical chemistry. A, 111(11), 2166-2171 (2007-03-29)
The catalytic system formed by tungstic acid and its complexes with H2O2 and phenylphosphonic acid has been analyzed from the experimental and theoretical points of view. Previous structural studies by XRD proved the validity of the DFT proposed models and
Shaopu Liu et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 19(7), 1055-1060 (2003-07-26)
In a weak acid medium, when an isopoly-tungstic acid reacts with berberine to form an ion-association complex, strong resonance Rayleigh scattering (RRS) appears and obvious frequency-doubling scattering (FDS) as well as second-order scattering (SOS) come into being. The scattering peaks
L V Del Priore et al.
Biochimica et biophysica acta, 845(1), 81-85 (1985-04-22)
Anionic activation of rod outer segment phosphodiesterase by vanadate, molybdate and tungstate is demonstrated. Comparisons are made to adenylate cyclase, which is known to be activated by vanadate and molybdate but not by tungstate. In view of the differences in
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