187070
2-Bromobenzyl bromide
98%
Synonym(s):
α,2-Dibromotoluene
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About This Item
Linear Formula:
BrC6H4CH2Br
CAS Number:
Molecular Weight:
249.93
Beilstein:
971015
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
98%
form
solid
refractive index
n20/D 1.619 (lit.)
bp
129 °C/19 mmHg (lit.)
mp
29-32 °C (lit.)
solubility
dioxane: soluble 1 g/10 mL, clear, colorless
functional group
bromo
SMILES string
BrCc1ccccc1Br
InChI
1S/C7H6Br2/c8-5-6-3-1-2-4-7(6)9/h1-4H,5H2
InChI key
LZSYGJNFCREHMD-UHFFFAOYSA-N
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General description
2-Bromobenzyl bromide is a reagent used to protect ketones and aldehydes in their less reactive alcohol oxidation states and as a coupling component in various reactions.
Application
2-Bromobenzyl bromide was used in the synthesis of:
- substituted quinazolines and 1,2,3,4-tetrahydroquinazolines
- 2- and 3-substituted indenes
- tris-2-bromotribenzylamine
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
235.4 °F - closed cup
Flash Point(C)
113 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Synthesis and structural studies of tris-2-chlorobenzylamine and tris-2-bromobenzylamine.
Chen Q, , et al.
Journal of Chemical Crystallography, 35(3), 177-181 (2005)
2-Bromobenzyl Bromide
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eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Xuesen Fan et al.
Chemistry, an Asian journal, 9(3), 739-743 (2014-01-01)
An efficient synthesis of diversely substituted quinazolines and 1,2,3,4-tetrahydroquinazolines through copper-catalyzed tandem reactions of the readily available 2-bromobenzyl bromides, aldehydes, and aqueous ammonia or amines has been developed. By using ammonia and simple aliphatic amines as the nitrogen source, the
Efficient synthesis of 2-and 3-substituted indenes from 2-bromobenzyl bromide through an enolate alkylation/Cr (II)/Ni (II)-mediated carbonyl addition sequence.
Halterman RLand Zhu C.
Tetrahedron Letters, 40(42), 7445-7448 (1999)
Prachi Singh et al.
SLAS discovery : advancing life sciences R & D, 22(4), 440-446 (2017-03-23)
Analysis of interactions between molecules is of fundamental importance in life science research. In this study, we applied weak affinity chromatography, based on high-performance liquid chromatography and mass spectrometry, as a powerful tool for direct analysis of the components of
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
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