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60591

Supelco

Potassium tetrakis(4-chlorophenyl)borate

Selectophore™, ≥98.0%

Synonym(s):

Tetrakis(4-chlorophenyl)boron potassium

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About This Item

Linear Formula:
(ClC6H4)4BK
CAS Number:
14680-77-4
Molecular Weight:
496.11
Beilstein:
4117827
EC Number:
238-723-0
MDL number:
MFCD00043105
UNSPSC Code:
26111700
PubChem Substance ID:
329759093
NACRES:
NB.61

grade

for ion-selective electrodes

Quality Level

200

product line

Selectophore™

Assay

≥98.0% (AT)
≥98.0%

form

solid

SMILES string

[K+].Clc1ccc(cc1)[B-](c2ccc(Cl)cc2)(c3ccc(Cl)cc3)c4ccc(Cl)cc4

InChI

1S/C24H16BCl4.K/c26-21-9-1-17(2-10-21)25(18-3-11-22(27)12-4-18,19-5-13-23(28)14-6-19)20-7-15-24(29)16-8-20;/h1-16H;/q-1;+1

InChI key

SAGICZRAKJSWLD-UHFFFAOYSA-N

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General description

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Application

Potassium tetrakis(4-chlorophenyl)borate was used as lipophilic anionic site in constructing fluorescent optode for sodium. It was also used as coating for the piezoelectric crystal in quantifying Potassium using quartz crystal microbalance.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Legal Information

Selectophore is a trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Skull and crossbones
GHS06

Signal Word

Danger

Hazard Statements

H301

Hazard Classifications

Acute Tox. 3 Oral

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCK3774
BCCJ3954
BCCJ6926
BCCF8665
BCCC7856

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B D Pendley et al.
Analytical chemistry, 73(19), 4599-4606 (2001-10-19)
A new chronoamperometric method is used to estimate changes in the membrane composition of mobile-site, ionophore-based membranes. The characteristic features of the chronoamperometric curves (initial current, slope, break time) of valinomycin-based, potassium-selective membranes loaded with potassium tetrakis(4-chlorophenyl)borate are correlated with
Qianyu Zhang et al.
Sensors (Basel, Switzerland), 13(6), 6936-6945 (2013-05-28)
A flow biosensor for the detection of toxicity in water using the ammonia-oxidizing bacterium (AOB) Nitrosomonas europaea as a bioreceptor and a polymeric membrane ammonium-selective electrode as a transducer is described. The system is based on the inhibition effects of
Larisa Lvova et al.
Sensors (Basel, Switzerland), 13(5), 5841-5856 (2013-05-09)
5,10,15,20-Tetraferrocenyl porphyrin, H2TFcP, a simple example of a donor-acceptor system, was tested as ligand for the development of a novel multi-transduction chemical sensors aimed at the determination of transition metal ions. The fluorescence energy transfer between ferrocene donor and porphyrin
Mihaela Dana Tutulea-Anastasiu et al.
Sensors (Basel, Switzerland), 13(4), 4367-4377 (2013-04-04)
All-solid-state sensors with polyvinyl chloride (PVC)-based membranes using off-the-shelf N-hydroxysuccinimide (NHS) and succinimide (Succ) ionophores were prepared using DOP (dioctyl phthalate) and NPOE (ortho-nitrophenyloctyl ether) as plasticizers. Good responses were obtained when NHS was used. The potentiometric response of the
R C Thomas et al.
Pflugers Archiv : European journal of physiology, 390(1), 96-98 (1981-04-01)
We have developed a filling solution for silanised microelectrodes consisting of potassium tetrakis (p-chlorophenyl) borate in octanol. Microelectrodes filled with this reference liquid ion-exchanger (RLIE) have equal selectivities to Na and K, and give the same membrane potential as do
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