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160997

Sigma-Aldrich

5,10,15,20-Tetraphenyl-21H,23H-porphine

97%

Synonym(s):

meso-Tetraphenylporphyrin, TPP

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About This Item

Empirical Formula (Hill Notation):
C44H30N4
CAS Number:
917-23-7
Molecular Weight:
614.74
Beilstein:
379542
EC Number:
213-025-9
MDL number:
MFCD00011680
UNSPSC Code:
12171500
PubChem Substance ID:
24849899
NACRES:
NA.47

Quality Level

100

Assay

97%

form

powder or crystals

impurities

1-3% corresponding chlorin

mp

>300 °C (lit.)

solubility

chloroform: 1 mg/mL, clear to opaque

λmax

514 nm

ε (extinction coefficient)

≥3500 at 480-486 nm in toluene
≥4000 at 647-653 nm in toluene
≥5000 at 589-595  nm in toluene
≥8000 at 546-552 nm in toluene

application(s)

diagnostic assay manufacturing
hematology
histology

storage temp.

room temp

SMILES string

c1ccc(cc1)-c2c3ccc(n3)c(-c4ccccc4)c5ccc([nH]5)c(-c6ccccc6)c7ccc(n7)c(-c8ccccc8)c9ccc2[nH]9

InChI

1S/C44H30N4/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36/h1-28,45,48H/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-

InChI key

YNHJECZULSZAQK-LWQDQPMZSA-N

Gene Information

human ... TERT(7015)

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General description

5,10,15,20-Tetraphenyl-21H,23H-porphine is a porphyrin compound.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
SHBR5475
MKCF4142
MKBP7614V
MKBC6522
25396TH

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G S S Saini et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 61(13-14), 3070-3076 (2005-09-17)
We present here the infrared absorption spectra of free-base tetraphenylporphine and its dication. Most of the allowed IR bands of porphyrin skeletal are observed in pairs due to two-fold symmetry of the free-base tetraphenylporphine. Observation of some new bands, disappearance
Pradip Chandra Mandal et al.
Journal of hazardous materials, 187(1-3), 600-603 (2011-02-09)
Reactions of nickel-5,10,15,20-tetraphenylporphine (Ni-TPP) were studied in supercritical water in the presence of toluene without the addition of any catalyst, H(2) or H(2)S that is called a green process. The objective of this study was to remove nickel from Ni-TPP
G S S Saini
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 64(4), 981-986 (2006-02-07)
Resonance Raman spectra of free-base tetraphenylporphine and its dication obtained with 441.6, 476.5, 488.0 and 514.5 nm excitation lines in the frequency region 100-1625 cm(-1) are reported. Some bands due to in-plane and out-of-plane vibrational modes, which are symmetry forbidden
Satoshi Tsukahara et al.
Analytical and bioanalytical chemistry, 395(4), 1047-1053 (2009-07-09)
Rhombic-ordered microdomains of diprotonated 5,10,15,20-tetraphenylporphine aggregate, whose sizes were 10-200 microm, were formed at dodecane/aqueous H(2)SO(4) interfaces. The light excitation of their two absorption bands (410 and 473 nm for H- and J-bands, respectively) led to one fluorescence band at
Maria Bassiouk et al.
Journal of nanoscience and nanotechnology, 11(6), 5457-5468 (2011-07-21)
The self-assembly of porphyrins into highly organized functional arrays supported on appropriate solid substrates is an area of research with multiple potential applications in the "bottom-up" approach to manufacturing. In order to analyze the self-assembly of meso-tetraphenylporphine (H2TPP) on the
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