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757144

Sigma-Aldrich

Vinylene carbonate

greener alternative

contains 80 ppm BHT as stabilizer, 99%

Synonym(s):

1,3-Dioxol-2-one, VC

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About This Item

Empirical Formula (Hill Notation):
C3H2O3
CAS Number:
872-36-6
Molecular Weight:
86.05
Beilstein:
105683
EC Number:
212-825-5
MDL number:
MFCD00005380
UNSPSC Code:
26111700
PubChem Substance ID:
329766650
NACRES:
NA.23

Assay

99%

form

liquid

contains

80 ppm BHT as stabilizer

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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refractive index

n20/D 1.421 (lit.)
n20/D 1.422

bp

162 °C (lit.)

mp

19-22 °C (lit.)

density

1.355 g/mL at 25 °C (lit.)
1.355 g/mL at 25 °C

application(s)

battery manufacturing

greener alternative category

, Enabling

storage temp.

2-8°C

SMILES string

O=C1OC=CO1

InChI

1S/C3H2O3/c4-3-5-1-2-6-3/h1-2H

InChI key

VAYTZRYEBVHVLE-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Vinylene carbonate (VC) can be used as an electrolytic additive for ionic liquid electrolyte for the formation of lithium-ion batteries. It can also be used in the formation of hybrid solid electrolyte interphase (SEI) for the fabrication of lithium-based batteries.

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Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 Oral

Target Organs

Liver,Stomach

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

181.9 °F - closed cup

Flash Point(C)

83.3 °C - closed cup

Certificates of Analysis (COA)

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Electrochemical investigations of ionic liquids with vinylene carbonate for applications in rechargeable lithium ion batteries
Sun X and Dai S
Electrochimica Acta, 55(15), 4618-4626 (2010)
Vinylene carbonate-LiNO3: a hybrid additive in carbonic ester electrolytes for SEI modification on Li metal anode
Guo J, et al.
Electrochemical Communications, 51(15), 59-63 (2015)
Matthieu Groh et al.
European journal of internal medicine, 26(7), 545-553 (2015-05-15)
To develop disease-specific recommendations for the diagnosis and management of eosinophilic granulomatosis with polyangiitis (Churg-Strauss syndrome) (EGPA). The EGPA Consensus Task Force experts comprised 8 pulmonologists, 6 internists, 4 rheumatologists, 3 nephrologists, 1 pathologist and 1 allergist from 5 European
Surface analytical study regarding the solid electrolyte interphase composition of nanoparticulate SnO2 anodes for Li-ion batteries
Winkler V, et al.
The Journal of Physical Chemistry C, 120(43), 24706-24714 (2016)
Stefan Hilf et al.
Journal of the American Chemical Society, 130(33), 11040-11048 (2008-07-24)
The selective placement of a functional group at the chain end of a ring-opening metathesis polymer using ruthenium carbene initiators has been a significant limitation. Here we demonstrate a highly effective and facile end-capping technique for ROMP with living ruthenium
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