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691348

Sigma-Aldrich

Basolite® Z1200

greener alternative

produced by BASF

Synonym(s):

2-Methylimidazole zinc salt, ZIF-8

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About This Item

Empirical Formula (Hill Notation):
C8H10N4Zn
CAS Number:
59061-53-9
Molecular Weight:
227.58
UNSPSC Code:
26111700
PubChem Substance ID:
329761400
NACRES:
NA.23

grade

produced by BASF

form

solid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

surface area

1300-1800 m2/g , Langmuir surf. area

particle size

4.9 μm (D50)

bulk density

0.35 g/cm3

greener alternative category

, Enabling

SMILES string

CC1=NC=C[N-]1.CC2=NC=C[N-]2.[Zn+2]

InChI

1S/2C4H5N2.Zn/c2*1-4-5-2-3-6-4;/h2*2-3H,1H3;/q2*-1;+2

InChI key

MFLKDEMTKSVIBK-UHFFFAOYSA-N

General description

Basolite(TM) Z1200 has a zeolitic imidazolate framework (ZIF) constituted of metal ions and imidazolate anions. The structure of ZIF is analogous to that of silica-zeolites. ZIFs have high thermal stability.
Metal organic framework (MOF)
Zinc imidazolate frameworks (ZIF)
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Basolite®Z1200 (ZIF-8) based MOFs can be used in the fabrication of matrix membranes for gas separation processes such as hydrogen separation, and nitrogen recovery. They are also used as fillers in the formation of PDMS based membranes for solvent resistant nanofitration (SRNF). They are commercially utilized as porous materials for the absorption and sensing of pesticides.
Used for separations (paraffin isomers, alkanes), sensors, and gas adsorption (hydrogen gas)

Other Notes

can be activated at 100°C (vacuum)

Legal Information

Basolite is a registered trademark of BASF SE

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302,H314

Hazard Classifications

Acute Tox. 4 Oral - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Molecular sieving realized with ZIF-8/Matrimid mixed-matrix membranes
Ordonez MJC, et al.
Journal of Membrane Science , 361(1-2), 28-37 (2010)
Doped Zinc-Organic Framework for Sensing of Pesticide
Kumar P, et al.
Advanced Materials Research, 488(1-2), 1543-1546 (2012)
Solvent resistant nanofiltration (SRNF) membranes based on metal-organic frameworks
Basu S, et al.
Journal of Membrane Science , 344(1-2), 190-198 (2009)
Peralta, D.; et al.
Industrial & Engineering Chemistry Research, 51, 4692-4702 (2012)
Julien Cousin-Saint-Remi et al.
ACS applied materials & interfaces, 11(14), 13694-13703 (2019-03-22)
Shaping metal-organic frameworks (MOFs) into robust particles with a controllable size is of large interest to the field of adsorption. Therefore, a method is presented here to produce robust MOF beads of different sizes, ranging from 250 μm to several
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Articles

Metal Organic Frameworks (MOFs)

Metal-organic frameworks (MOFs) are porous, crystalline materials composed of metal ions bound by organic ligands.

Metal Organic Frameworks (MOFs)

Metal-organic frameworks (MOFs) are porous, crystalline materials composed of metal ions bound by organic ligands.

Metal Organic Frameworks (MOFs)

Metal-organic frameworks (MOFs) are porous, crystalline materials composed of metal ions bound by organic ligands.

Metal Organic Frameworks (MOFs)

Metal-organic frameworks (MOFs) are porous, crystalline materials composed of metal ions bound by organic ligands.

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