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567205

Sigma-Aldrich

Tetramethylthiuram monosulfide

97%

Synonym(s):

UNADS

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About This Item

Linear Formula:
((H3C)2NCS)2S
CAS Number:
97-74-5
Molecular Weight:
208.37
EC Number:
202-605-7
MDL number:
MFCD00014870
UNSPSC Code:
12352100
PubChem Substance ID:
24880353
NACRES:
NA.22

Assay

97%

mp

107-111 °C (lit.)

SMILES string

CN(C)C(=S)SC(=S)N(C)C

InChI

1S/C6H12N2S3/c1-7(2)5(9)11-6(10)8(3)4/h1-4H3

InChI key

REQPQFUJGGOFQL-UHFFFAOYSA-N

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Related Categories

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302,H317,H410

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

312.8 °F - closed cup

Flash Point(C)

156 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Allergic contact dermatitis of the eyelids from rubber chemicals.
J C Cabrita et al.
Contact dermatitis, 24(2), 145-146 (1991-02-01)
E Schreiner et al.
Toxicology letters, 25(2), 147-152 (1985-05-01)
The epoxide hydrolase (EH) activity in the liver of adult female Wistar rats significantly increased 18 h after the administration by gavage of tetramethyl thiuramdisulfide (TMTD, 1 mmol/kg) or tetramethyl thiurammonosulfide (TMTM, 2 mmol/kg). No increase was observed 5 h
Q Li et al.
Toxicology, 104(1-3), 17-23 (1995-12-15)
To examine the validity of a modified lymphocyte transformation test for evaluating contact hypersensitivity from weak sensitizers, guinea pigs were sensitized with formaldehyde (F) or tetramethylthiuram monosulfide (TMTM) using the maximization test procedure. Lymph node cells from the animals were
Contact allergy to Nobecutan.
B Pock-Steen
Contact dermatitis, 18(1), 52-53 (1988-01-01)
B B Knudsen et al.
Contact dermatitis, 34(6), 410-413 (1996-06-01)
An estimate of amounts of thiurams that may be released from rubber gloves into synthetic sweat, has previously been generated. These amounts should be compared to elicitation thresholds of patch tests performed with serial dilutions of thiuram mix using synthetic
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