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499811
Lithium
granular, 99% trace metals basis
Synonym(s):
Lithium atom, Lithium element
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About This Item
Linear Formula:
Li
CAS Number:
Molecular Weight:
6.94
EC Number:
MDL number:
UNSPSC Code:
12141803
PubChem Substance ID:
NACRES:
NA.23
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Quality Level
Assay
99% trace metals basis
form
granular
reaction suitability
reagent type: reductant
resistivity
9.446 μΩ-cm, 20°C
bp
1342 °C (lit.)
mp
180 °C (lit.)
density
0.534 g/mL at 25 °C (lit.)
SMILES string
[Li]
InChI
1S/Li
InChI key
WHXSMMKQMYFTQS-UHFFFAOYSA-N
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General description
Granular lithium is a form of lithium metal that has been ground into small granules. Lithium is a soft, silver-white metal that is highly reactive and flammable. Lithium has a low density of 0.534 g/cm3, which makes it one of the lightest metals. Like the other alkali metals, lithium has a low melting point (180 °C) and is a good conductor of electricity and heat. Granular lithium is highly reactive and behaves as a strong reducing agent. It must be handled with caution due to its potential to ignite or explode. Lithium reacts readily with water and oxygen to form lithium hydroxide and lithium oxide, respectively, and even reacts with nitrogen gas at room temperature, forming lithium nitride. Typically, lithium is stored in an argon glovebox and airtight containers to prevent exposure to moisture, air, and nitrogen. To make granular lithium, the metal is first extracted from ores such as spodumene or lepidolite using a process called lithium carbonate conversion. After the lithium has been purified to a high degree of purity, it is milled into granules by rotating blades.
Lithium is a low-density alkali metal that is widely used as an anode material in rechargeable and non-rechargeable batteries. It is also used to alloy with aluminum and magnesium to make them stronger and lighter.
Application
Lithium can be used as:
- A precursor to synthesize Li-based alloys such as LiAl and LiSi alloys, which are applicable as anode materials in the field of energy conversion and storage.[1]
- A reducing agent in the reduction of zirconium oxide compounds in molten LiCl salt.[2]
- As starting material to synthesize a reducing agent(1,4-bis(trimethylgermyl)-1.4-dihydropyrazine), for the fabrication of nickel metal films.[3]
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B - Water-react 1
Supplementary Hazards
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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A low-temperature thermal ALD process for nickel utilizing dichlorobis(triethylphosphine)nickel(ii) and 1{,}4-bis(trimethylgermyl)-1{,}4-dihydropyrazine"
Anton Vihervaara,
Dalton Transactions, 51, 10898-10908 (2022)
Reduction of zirconium oxide compounds by lithium metal as a reductant in molten LiCl salt
Eun-Young Choi and Dong Hyun Heo
Journal of Nuclear Materials, 512, 193-198 (2018)
Anode performance of lithium--silicon alloy prepared by mechanical alloying for use in all-solid-state lithium secondary batteries
Hye Won Park, et al.
Japanese Journal of Applied Physics, 53, 08NK02-08NK02 (2014)
Dongyun Chen et al.
Nanoscale, 5(17), 7890-7896 (2013-07-16)
Two-dimensional nanosheets can leverage on their open architecture to support facile insertion and removal of Li(+) as lithium-ion battery electrode materials. In this study, two two-dimensional nanosheets with complementary functions, namely nitrogen-doped graphene and few-layer WS2, were integrated via a
Sureshbabu Guduguntla et al.
The Journal of organic chemistry, 78(17), 8274-8280 (2013-08-22)
An efficient one-pot synthesis of optically active β-alkyl-substituted alcohols through a tandem copper-catalyzed asymmetric allylic alkylation (AAA) with organolithium reagents and reductive ozonolysis is presented. Furthermore, hydroboration-oxidation following the Cu-catalyzed AAA leads to the corresponding homochiral γ-alkyl-substituted alcohols.
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This lithium is stated to be granular. What is the average particle diameter of the granules?
1 answer-
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What atmosphere is the granular lithium (product 499811-25G) shipped under? Specifically, is it under an inert atmosphere in the bottle, or under a natural atmosphere?
1 answer-
The granular lithium (product 499811-25G) is packaged under argon, which provides an inert atmosphere within the bottle.
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Greeting! Where could i found expiration date?
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This product is not assigned an expiration date or recommended retest date. Products with no expiration date or recommended retest date should be routinely inspected by customers to ensure they perform as expected. These products are also subject to a one-year warranty from the date of shipment.
For more information, you may access the "Product Dating Information" document under "ADDITIONAL USEFUL DOCUMENTS ABOUT OUR PRODUCTS" at the bottom of the Quality Services page with this link: https://www.sigmaaldrich.com/life-science/quality-and-regulatory-management/quality-services.
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