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482293

Sigma-Aldrich

Tetraammineplatinum(II) nitrate

99.995% trace metals basis

Synonym(s):

Platinum tetraamine dinitrate, Tetraamineplatinum(II) dinitrate, Tetraamminedinitratoplatinum

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About This Item

Linear Formula:
[Pt(NH3)4](NO3)2
CAS Number:
Molecular Weight:
387.21
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Assay

99.995% trace metals basis

form

solid

reaction suitability

core: platinum
reagent type: catalyst

mp

262 °C (dec.) (lit.)

SMILES string

N.N.N.N.[Pt++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/2NO3.4H3N.Pt/c2*2-1(3)4;;;;;/h;;4*1H3;/q2*-1;;;;;+2

InChI key

RBAKORNXYLGSJB-UHFFFAOYSA-N

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Application

Tetraammineplatinum(II) nitrate can be used as a platinum (Pt) precursor to synthesize platinum-based catalysts such as Pt/cerium oxide catalysts and Pt/mesoporous carbon catalysts. It is also used in synthesizing lean NOx trap (LNT) catalysts.

Pictograms

Exploding Bomb

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Chronic 3 - Org. Perox. A

Supplementary Hazards

Storage Class Code

4.1A - Other explosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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NOx storage and reduction properties of model ceria-based lean NOx trap catalysts.
Shi C, et al.
Applied Catalysis. B, Environmental, 119, 183-196 (2012)
Preparation of Pt/mesoporous carbon (MC) electrode catalyst and its reactivity toward oxygen reduction.
Hayashi A, et al.
Electrochimica Acta, 53(21), 6117-6125 (2008)
High performance monolithic catalysts for hydrogenation reactions.
Perez-Cadenas A F, et al.
Catalysis Today, 105(3-4), 623-628 (2005)
L X Yang et al.
International journal of radiation oncology, biology, physics, 33(3), 641-646 (1995-10-15)
Because radiation is known to damage cellular membranes, the purpose of this study was to determine whether irradiation of cultured cells might modify the cellular uptake of the chemotherapy agent carboplatin. Total intracellular platinum was measured using atomic absorption spectrometry
Austin B Yongye et al.
Journal of computer-aided molecular design, 24(3), 225-235 (2010-03-25)
The potential energy surfaces of chiral tetraamine Pt(II) coordination complexes were computed at the B3LYP/LANL2DZ level of theory by a systematic variation of two dihedral angles: C12-C15-C34-C37 (theta) and C24-C17-C31-C48 (psi) employing a grid resolution of 30 degrees . Potential

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