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Key Documents

383767

Sigma-Aldrich

Tri(2-furyl)phosphine

99%

Synonym(s):

TFP, Tri-2-furanylphosphine, Tris(2-furanyl)phosphine, Tris(o-furyl)phosphine

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About This Item

Empirical Formula (Hill Notation):
C12H9O3P
CAS Number:
Molecular Weight:
232.17
Beilstein:
1577564
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22

Assay

99%

form

solid

reaction suitability

reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction

reagent type: ligand
reaction type: Cycloisomerizations

reagent type: ligand
reaction type: Heck Reaction

reagent type: ligand
reaction type: Negishi Coupling

reagent type: ligand
reaction type: Oxidations

reagent type: ligand
reaction type: Sonogashira Coupling

reagent type: ligand
reaction type: Stille Coupling

reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

bp

136 °C/4 mmHg (lit.)

mp

59-64 °C (lit.)

functional group

phosphine

SMILES string

c1coc(c1)P(c2ccco2)c3ccco3

InChI

1S/C12H9O3P/c1-4-10(13-7-1)16(11-5-2-8-14-11)12-6-3-9-15-12/h1-9H

InChI key

DLQYXUGCCKQSRJ-UHFFFAOYSA-N

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Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Paul W Peterson et al.
Journal of the American Chemical Society, 138(48), 15617-15628 (2016-12-10)
Generally, the long-range electronic communication between spatially orthogonal orbitals is inefficient and limited to field and inductive effects. In this work, we provide experimental evidence that such communication can be achieved via intramolecular electron transfer between two degenerate and mutually
Hajime Monzen et al.
Journal of applied clinical medical physics, 18(5), 325-329 (2017-06-29)
Tungsten functional paper (TFP) is a novel paper-based radiation-shielding material. We measured the shielding ability of TFP against x-rays and gamma rays. The TFP was supplied in 0.3-mm-thick sheets that contained 80% tungsten powder and 20% cellulose (C
Liang-da Chiu et al.
Scientific reports, 7, 43569-43569 (2017-03-09)
Our current understanding of molecular biology provides a clear picture of how the genome, transcriptome and proteome regulate each other, but how the chemical environment of the cell plays a role in cellular regulation remains much to be studied. Here
Jingwen Jiang et al.
DNA and cell biology, 36(10), 813-821 (2017-09-07)
Schizophrenic patients tend to have reduced incidence of some cancers due to the treatment of antipsychotic drugs with antitumor effects, such as chlorpromazine and trifluoperazine (TFP). Forkhead Box O1 (FOXO1) as tumor suppressor in many malignancies is often inactivated by
Na Zhang et al.
International journal of environmental research and public health, 17(10) (2020-05-21)
Green development is an important way to meet the challenges of ecological and environmental protection and economic growth, as well as an inevitable choice to realize China's sustainable development in the new era. The Chinese economic system is such that

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