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225444

Sigma-Aldrich

2-Phenylbenzothiazole

97%

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About This Item

Empirical Formula (Hill Notation):
C13H9NS
CAS Number:
Molecular Weight:
211.28
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

97%

form

solid

mp

111-113 °C (lit.)

SMILES string

c1ccc(cc1)-c2nc3ccccc3s2

InChI

1S/C13H9NS/c1-2-6-10(7-3-1)13-14-11-8-4-5-9-12(11)15-13/h1-9H

InChI key

XBHOUXSGHYZCNH-UHFFFAOYSA-N

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Application

2-Phenylbenzothiazole was used in the synthesis of two novel orange iridium(III) complexes, (bis[2-(biphenyl-3-yl)benzothiazole-N,C2′]iridium(III)(acetylacetonate) and bis[2-(4′-methoxybiphenyl-3-yl)benzothiazole-N,C2′]iridium(III) (acetylacetonate).

Storage Class Code

11 - Combustible Solids

WGK

WGK 3


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Jun Dai et al.
Dalton transactions (Cambridge, England : 2003), 42(29), 10559-10571 (2013-06-14)
By introducing a phenyl substituent into the meta-site of the phenyl segment of the 2-phenylbenzothiazole ligand, two novel orange iridium(III) complexes, namely, (3Phbt)2Ir(acac) and (3OMePhbt)2Ir(acac), have been synthesized. Compared with their parent compound (bt)2Ir(acac), both of them possess much enhanced
Ming Li et al.
Dalton transactions (Cambridge, England : 2003), 40(27), 7153-7164 (2011-06-15)
Four novel iridium(III) complexes bearing biphenyl (7a-7c) or fluorenyl (7d) modified benzothiazole cyclometallate ligands are synthesized. In comparison with the yellow parent complex, bis(2-phenylbenzothiozolato-N,C(2')) iridium(III) (acetylacetonate) [(pbt)(2)Ir(acac)] (λ(PLmax) = 557 nm, φ(PL) = 0.26), 7a-7d show 20-43 nm bathochromic shifted
Rupam Sarma et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 77(1), 126-129 (2010-06-16)
The UV-visible and fluorescence properties of hydroxy substituted benzothiazole derivatives change on interactions with zinc(II), cadmium(II) and mercury(II) ions. The binding of 2-(2'-hydroxyphenyl)benzothiazole is specific to zinc(II) over cadmium(II) and mercury(II). Similar type of interactions of zinc(II), cadmium(II) and mercury(II)
P Ivanov et al.
Journal of fluorescence, 22(6), 1501-1507 (2012-07-10)
The parent study includes synthesis end photophysical characterization of four new phosphorescent cyclometalated iridium (III) complexes. The cyclometaled ligands used here are 2-(4-chlorophenyl)benzo[d]thiazole, 2(4isopropylphenyl)benzo[d] thiazole, 2-(4-methoxyphenyl)benzo[d]thiazole, 4-(benzo[d]thiazol-2-yl)-N,N-dimethylaniline. The auxiliary ligand is acetylacetone (Hacac). The photometric analyses show temperature dependence on
Stamatia Tzanopoulou et al.
Inorganic chemistry, 45(2), 902-909 (2006-01-18)
The reaction of 2-(2'-pyridyl)benzothiazole, [NN], with the ReO(V)(3+) and TcO(V)(3+) cores in the presence of thiophenols, [S] (RC(6)H(4)SH, R = H, 4-CH(3), 4-OCH(3)), as coligands led to the isolation of hexacoordinated complexes of the MO[NN][S](3) type (M = Re, Tc).

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