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199478

Sigma-Aldrich

Germanium(IV) oxide

(crystalline powder), 99.998% trace metals basis

Synonym(s):

Germanium dioxide

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About This Item

Linear Formula:
GeO2
CAS Number:
1310-53-8
Molecular Weight:
104.64
EC Number:
215-180-8
MDL number:
MFCD00011030
UNSPSC Code:
12352303
PubChem Substance ID:
24851918
NACRES:
NA.23

Assay

99.998% trace metals basis

form

(crystalline powder)

mp

>400 °C (lit.)

density

4.23 g/cm3

application(s)

battery manufacturing

SMILES string

O=[Ge]=O

InChI

1S/GeO2/c2-1-3

InChI key

YBMRDBCBODYGJE-UHFFFAOYSA-N

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Application

Germanium(IV) oxide can be used:
  • To prepare glasses for nuclear radiation shielding and ultra-broadband amplification. For example, germanium and bismuth oxide glasses.
  • As a precursor to synthesize GeO2/TiO2 nanocomposites that can be used for the photocatalysis of organic pollutants.
  • As an anode material for lithium-ion batteries due to its high lithium storage capacity, thermostability, and large volume expansion during the charge–discharge process.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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P. M. Lambert
Inorganic chemistry, 37(6), 1352-1357 (2001-10-24)
The gel chemistry of germanium is explored through the formation and composition of a hydrous metal oxide precursor gel used in the preparation of the HfGeO(4) and HfGeO(4):Ti X-ray phosphors. The enhanced solubility of hexagonal GeO(2) in dilute ammoniacal solutions
Zita Oláh et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 149, 75-82 (2019-04-29)
The radiochemical separation of n.c.a. arsenic on its own or for radio-labelling purposes usually involves the issue of reducing arsenic(V). Numerous approaches for reducing pentavalent arsenic have been examined. A novel HPLC method has also been presented for accessing the
V V Dvoyrin et al.
Optics express, 19(9), 7992-7999 (2011-06-07)
A novel all-fiber laser based on a highly GeO2-doped dispersion-shifted Tm-codoped fiber, pumped at 1.56 µm wavelength and lasing at 1.862 µm wavelength with a slope efficiency up to 37% was demonstrated. The single-mode Tm-doped fiber with the 55GeO2-45SiO2 core
M Gunji et al.
Nanotechnology, 23(38), 385603-385603 (2012-09-06)
We report on the directed synthesis of germanium oxide (GeO(x)) nanowires (NWs) by locally catalyzed thermal oxidation of aligned arrays of gold catalyst-tipped germanium NWs. During oxygen anneals conducted above the Au-Ge binary eutectic temperature (T > 361 °C), one-dimensional
Xinguo Hong et al.
The Review of scientific instruments, 80(7), 073908-073908 (2009-08-07)
We describe an approach for acquiring high quality x-ray absorption fine structure (XAFS) spectroscopy spectra with wide energy range at high pressure using diamond anvil cell (DAC). Overcoming the serious interference of diamond Bragg peaks is essential for combining XAFS
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