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134341

Sigma-Aldrich

4-Phenylphenol

97%

Synonym(s):

4-Hydroxybiphenyl

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About This Item

Linear Formula:
C6H5C6H4OH
CAS Number:
92-69-3
Molecular Weight:
170.21
Beilstein:
1907452
EC Number:
202-179-2
MDL number:
MFCD00002347
UNSPSC Code:
12352100
eCl@ss:
39023323
PubChem Substance ID:
24848146
NACRES:
NA.22

Assay

97%

bp

321 °C (lit.)

mp

164-166 °C (lit.)

solubility

methanol: soluble 50 mg/mL, clear, colorless

SMILES string

Oc1ccc(cc1)-c2ccccc2

InChI

1S/C12H10O/c13-12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-9,13H

InChI key

YXVFYQXJAXKLAK-UHFFFAOYSA-N

Gene Information

rat ... Ar(24208)

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General description

4-Phenylphenol undergoes enzymatic polymerization and polymer developed is characterized by matrix-assisted laser desorption ionization time-of-flight mass spectrometry. It is the intermediate in manufacture of 4-alkyl substituted phenol-formaldehyde resins.

Application

4-Phenylphenol was used in the synthesis of a novel polyphosphazene polyelectrolyte as a dispersing agent of single-walled carbon nanotubes in water.

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H315,H317,H411

Hazard Classifications

Aquatic Chronic 2 - Skin Irrit. 2 - Skin Sens. 1B

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 2

Flash Point(F)

320.0 °F - closed cup

Flash Point(C)

160 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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MALDI-TOF mass spectrometry characterization of 4-alkyl substituted phenol-formaldehyde novalac type resins.
Mandal H and Hay AS.
Polymer, 38(26), 6267-6271 (1997)
Dispersion of single-walled carbon nanotubes in water with polyphosphazene polyelectrolyte.
Park HJ, et al.
Journal of Inorganic and Organometallic Polymers and Materials, 16(4), 359-364 (2006)
Peng Xu et al.
Biomacromolecules, 3(5), 889-893 (2002-09-10)
Matrix-assisted laser desorption ionization time-of-flight (MALDI-TOF) mass spectrometry is a powerful tool for polymer characterization. It has been used to understand the enzymatic polymerization of 4-phenylphenol and to monitor number average molecular weight and weight average molecular weight of the
Minoru Yamaji
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 7(6), 711-717 (2008-06-06)
The photochemical properties of alpha-cleavage of C-O bond in highly excited triplet states (T(n) with n>2) of p-biphenyl acetate and p-biphenyl benzoate (Me-OBP and Ph-OBP) in solution were investigated in comparison with those in the lowest excited singlet and triplet
Minoru Yamaji et al.
The journal of physical chemistry. A, 112(45), 11306-11311 (2008-10-17)
Photochemical properties of p-phenylphenacyl derivatives (PP-X) having C-halide, C-S, and C-O bonds in the lowest (T 1) and higher (T n ) triplet excited states were investigated in solution by using single-color and stepwise two-color two-laser flash photolysis techniques. PP-Xs
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