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CRM04195

Supelco

Dichlofluanid

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

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About This Item

Empirical Formula (Hill Notation):
C9H11Cl2FN2O2S2
CAS Number:
Molecular Weight:
333.23
Beilstein:
2947992
MDL number:
UNSPSC Code:
41116107
NACRES:
NA.24

grade

certified reference material
TraceCERT®

Quality Level

product line

TraceCERT®

shelf life

limited shelf life, expiry date on the label

manufacturer/tradename

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

storage temp.

2-8°C

SMILES string

CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)c1ccccc1

InChI

1S/C9H11Cl2FN2O2S2/c1-13(2)18(15,16)14(17-9(10,11)12)8-6-4-3-5-7-8/h3-7H,1-2H3

InChI key

WURGXGVFSMYFCG-UHFFFAOYSA-N

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General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ. Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate. Download your certificate at: http://www.sigma-aldrich.com

Dichlofluanid is a booster biocide that belongs to the sulfamide class. It binds with thiol groups, including the tripeptide glutathione, to inhibit mitochondrial respiration and lipid peroxidation.

Dichlofluanid is widely used in agriculture to control scab, brown rot, and storage diseases in apples and pears, Botrytis spp., Alternaria spp., Clasterosporium spp., downy mildew, etc. in vines, pome fruit, stone fruit, berries, strawberries, hops, tomatoes, cucurbits, vegetables, ornamentals, and conifer seedbeds.

Dichlofluanid is not approved in the European Union. A default MRL of 0.01 mg/kg has been set according to Art 18(1)(b) Reg. 396/2005.

Application

It is intended to be used as a certified reference material (CRM) for calibration in chromatography and other analytical techniques. Dichlofluanid CRM may also find its use as described below:
  • To determine the concentration of dichlofluanid and its metabolite in seawater and sediment of three marinas in Greece before and during the yachting season
  • To evaluate the biochemical and physiological effects of dichlofluanid exposure on the brown mussel Perna perna
  • Photocatalytic degradation of chlorothalonil and dichlofluanid over TiO2 suspensions
  • Testing toxicity of the fungicides penconazol, cymoxanil, and dichlofluanid and their effects on the specific growth rate, biomass production, respiration rate, and yeast viability
  • To estimate the rates of disappearance of dichlofluanid and tebuconazole following successive applications to two varieties of lettuce grown in greenhouse conditions

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation markEnvironment

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Acute 1 - Eye Irrit. 2 - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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C Hamwijk et al.
Chemosphere, 60(9), 1316-1324 (2005-07-16)
Dichlofluanid (N-dichlorofluoromethylthio-N'-dimethyl-N-phenylsulphamide) is used as booster biocide in antifouling paints. The occurrence of dichlofluanid and its metabolite DMSA (N'-dimethyl-N-phenyl-sulphamide) was monitored in seawater and marine sediment from three Greek marinas. Seawater and sediment samples were collected at three representative positions
Regina Coimbra Rola et al.
Marine pollution bulletin, 157, 111321-111321 (2020-07-14)
Dichlofluanid is a fungicide employed as a booster biocide in antifouling paints, but information its toxicity to aquatic organisms is scarce. This study aims to evaluate biomarker responses in the mussel Perna perna exposed to dichlofluanid. Mussels were exposed to
Raquel Rial-Otero et al.
Journal of agricultural and food chemistry, 53(11), 4471-4475 (2005-05-26)
Residual levels and degradation rates of tebuconazole and dichlofluanid in lettuce plants grown in a greenhouse under agricultural conditions typical of northwestern Spain were studied. Lettuce plants were sprayed four times with a homogeneous 0.2% aqueous solution of Folicur Combi
Photocatalyzed degradation of the biocides chlorothalonil and dichlofluanid over aqueous TiO2 suspensions
Sakkas VA and Albanis TA
Applied Catalysis. B, Environmental, 175-188 null
I C Ribeiro et al.
Chemosphere, 41(10), 1637-1642 (2000-11-01)
In the present work the sensitivity of yeast strains of Kluyveromyces marxianus, Pichia anomala, Candida utilis, Schizosaccharomyces pombe and Saccharomyces cerevisiae, to the fungicides cymoxanil, penconazol, and dichlofluanid, was evaluated. Dichlofluanid induced the most negative effects, whereas penconazol in general

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