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Supelco

Tolylfluanid

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C10H13Cl2FN2O2S2
CAS Number:
731-27-1
Molecular Weight:
347.26
Colour Index Number:
45430
Beilstein:
2949607
EC Number:
211-986-9
MDL number:
MFCD00055477
UNSPSC Code:
41116107
PubChem Substance ID:
329753720
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)c1ccc(C)cc1

InChI

1S/C10H13Cl2FN2O2S2/c1-8-4-6-9(7-5-8)15(18-10(11,12)13)19(16,17)14(2)3/h4-7H,1-3H3

InChI key

HYVWIQDYBVKITD-UHFFFAOYSA-N

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General description

Tolylfluanid is a phenylsulfamide fungicide, generally used in fertilizers. It can also be used as an antifouling agent in vessel paints.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Tolylfluanid may be used as a reference standard for the determination of the analyte in nutraceutical formulations using dispersive liquid-liquid microextraction(DLLME) coupled with gas chromatography-mass spectrometry method.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Aquatic Acute 1 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ3200
BCCB7968
BCBZ7089
BCBT9907
SZBD038XV

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Sigma-Aldrich

H3274

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Aurélie Berthet et al.
Toxicology letters, 324, 38-45 (2020-02-18)
Tolylfluanid (TF) is a sensitizing biocide used in antifouling products and wood preservatives. Paint application is associated with skin exposure; however, the importance of this exposure route is uncertain as TF skin permeation rates are lacking in the peer-reviewed scientific
Increase in intracellular Ca2+ level by phenylsulfamide fungicides, tolylfluanid and dichlofluanid, in rat thymic lymphocytes.
Fukunaga E, et al,
Environmental Toxicology and Pharmacology, 40(1), 149- 155 (2015)
Dispersive liquid-liquid microextraction followed by gas chromatography- mass spectrometry for the determination of pesticide residues in nutraceutical drops.
Szarka A, et al.
Journal of Chromatography A, 1570(1), 126- 134 (2018)
Ali Kadar et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 1113, 69-76 (2019-03-23)
In this study, an accurate and robust gas chromatography/mass spectrometry method was developed for quantitative analysis of diphenylamine, tolylfluanid, propargite and phosalone in liver fractions. Different injector parameters were optimized by an experimental design technique (central composite design). An optimal
E Tielemans et al.
American Industrial Hygiene Association journal, 60(6), 789-793 (2000-01-15)
As part of a European Concerted Action on Male Reproduction Capability an exposure assessment survey was conducted among seasonal workers in the fruit growing sector in the Netherlands. Dermal exposure to the fungicides captan and tolylfluanid was measured using cotton
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