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238295

Sigma-Aldrich

1-Iodooctane

98%

Synonym(s):

Octyl iodide

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About This Item

Linear Formula:
CH3(CH2)7I
CAS Number:
Molecular Weight:
240.13
Beilstein:
1697479
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

98%

form

liquid

contains

copper as stabilizer

refractive index

n20/D 1.4878 (lit.)

bp

225-226 °C (lit.)

mp

−46-−45 °C (lit.)

density

1.33 g/mL at 25 °C (lit.)

functional group

alkyl halide
iodo

SMILES string

CCCCCCCCI

InChI

1S/C8H17I/c1-2-3-4-5-6-7-8-9/h2-8H2,1H3

InChI key

UWLHSHAHTBJTBA-UHFFFAOYSA-N

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General description

1-Iodooctane undergoes catalytic reduction by nickel (I) salen electrogenerated at a glassy carbon cathode in dimethylformamide. Radical mechanism of formation of monolayer on silicon ground in the presence of 1-iodooctane has been studied by X-ray photoelectron spectroscopy.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

188.6 °F - closed cup

Flash Point(C)

87 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Evidence for a radical mechanism in monolayer formation on silicon ground (or scribed) in the presence of alkyl halides.
Jiang G, et al.
Langmuir, 20(5), 17772-17774 (2004)
Catalytic reduction of 1-iodooctane by nickel (I) salen electrogenerated at carbon cathodes in dimethylformamide: Effects of added proton donors and a mechanism involving both metal-and ligand-centered one-electron reduction of nickel (II) salen.
Raess PW, et al.
Journal of Electroanalytical Chemistry, 603(1), 124-134 (2007)
Alexa Schmitz et al.
ChemistryOpen, 10(2), 153-163 (2020-12-24)
S-alkyltetrahydrothiophenium, [Cn THT]+ bis(trifluorosulfonyl)imide, [NTf2 ]- room temperature ionic liquids (ILs) and tetraphenylborate, [BPh4 ]- salts with alkyl chain lengths from C4 to C10 have been prepared. The ILs and salts were characterized and their purity verified by 1 H-
Robert Löwe et al.
Molecules (Basel, Switzerland), 24(2) (2019-01-20)
Eight new polymerizable ammonium-TFSI ionic liquids were synthesized and characterized with respect to an application in energy storage devices. The ionic liquids feature methacrylate or acrylate termination as polymerizable groups. The preparation was optimized to obtain the precursors and ionic

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