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Merck

217263

Sigma-Aldrich

Sodium thiosulfate

ReagentPlus®, 99%

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About This Item

Fórmula lineal:
Na2S2O3
Número de CAS:
Peso molecular:
158.11
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21

product line

ReagentPlus®

assay

99%

form

powder, crystals or chunks

pH

6.0-8.5 (20 °C, 50 g/L)

SMILES string

[Na+].[Na+].[O-]S([O-])(=O)=S

InChI

1S/2Na.H2O3S2/c;;1-5(2,3)4/h;;(H2,1,2,3,4)/q2*+1;/p-2

InChI key

AKHNMLFCWUSKQB-UHFFFAOYSA-L

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General description

Sodium thiosulfate is an inorganic salt composed of thiosulfate and sodium ion with the chemical formula Na2S2O3. It is general reducing agent and useful sulfur source in synthetic chemistry

Application

Applied in a widely useful, thiosulfate-assisted, synthesis of a variety of diamine-CuCN complexes.
Sodium thiosulfate can be used as a
  • Component in the synthesis of unsymmetrical aryl sulfides under aqueous conditions, where C–S–C bond formed in presence of other two components (alcohols and organohalides).
  • Reagent for the activation of carbon material.
  • Reagent in the synthesis of S-glycosyl thiosulfates (glycosyl bunte salts) by direct condensation of unprotected sugars using dehydrating agent DMC (2-chloro-1,3-dimethylimidazolinium chloride) in water-acetonitrile solvent mixture.
  • Reagent with alkyl halide in the synthesis of Bunte salts by SN2 mechanism using Cu catalyst.
  • Reagent in the synthesis of aryl thiols from aryl halides by palladium catalyzed cross-coupling reaction.

Features and Benefits

Sodium thiosulfate is:
  • Stable
  • Environmentally friendly
  • Odorless
  • Inexpensive.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Storage Class

11 - Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


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