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Merck

06203

Sigma-Aldrich

Hidróxido de sodio

puriss., meets analytical specification of Ph. Eur., BP, NF, E524, 98-100.5%, pellets

Sinónimos:

«Sosa cáustica»

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About This Item

Fórmula lineal:
NaOH
Número de CAS:
Peso molecular:
40.00
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21

vapor density

>1 (vs air)

Quality Level

vapor pressure

<18 mmHg ( 20 °C)
3 mmHg ( 37 °C)

grade

puriss.

assay

98-100.5%

form

pellets

quality

meets analytical specification of Ph. Eur., BP, NF, E524

impurities

≤0.0005% total nitrogen (N)
≤0.002% heavy metals (as Pb)
≤0.5% Na2CO3

mp

318 °C (lit.)

solubility

water: soluble 1260 g/L at 20 °C

density

2.13 g/cm3 at 20 °C

anion traces

chloride (Cl-): ≤20 mg/kg
phosphate (PO43-): ≤10 mg/kg
silicate (as SiO2): ≤100 mg/kg
sulfate (SO42-): ≤30 mg/kg

cation traces

Al: ≤10 mg/kg
As: ≤2 mg/kg
Ca: ≤10 mg/kg
Fe: ≤10 mg/kg
Hg: ≤1 mg/kg
K: ≤1000 mg/kg
Pb: ≤0.5 mg/kg

SMILES string

[OH-].[Na+]

InChI

1S/Na.H2O/h;1H2/q+1;/p-1

InChI key

HEMHJVSKTPXQMS-UHFFFAOYSA-M

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General description

Sodium hydroxide, also known as lye and caustic soda, is a strong base used universally as a neutralization agent in the chemical industry, paper making, petroleum refining, cleaning compounds, and drain cleaners.

Application

Sodium hydroxide can be used as:
  • A reagent in the gold-catalyzed selective oxidation of glycerol to glyceric acid.
  • A catalyst for the cross-dehydrogenative coupling of alcohols and hydrosilanes to synthesize silyl ethers.
  • A base in the transition-metal free Sonogashira-type couplings of aryl halides and alkynes to synthesize ynones in the presence of PEG as a phase-transfer agent.

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificados de análisis (COA)

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Chemoselective, solvent-free aldol condensation reaction.
Raston CL and Scott JL.
Green Chemistry, 2(2), 49-52 (2000)
Determination of specific surface area of colloidal silica by titration with sodium hydroxide.
Sears Jr GW.
Analytical Chemistry, 28(12), 1981-1983 (1956)
Kinetics of sodium borohydride direct oxidation and oxygen reduction in sodium hydroxide electrolyte: Part I. BH4- electro-oxidation on Au and Ag catalysts.
Chatenet M, et al.
Electrochimica Acta, 51(25), 5459-5467 (2006)
M A Roberts et al.
Analytical chemistry, 69(11), 2035-2042 (1997-06-01)
This report describes a UV laser photoablation method for the production of miniaturized liquid-handling systems on polymer substrate chips. The fabrication of fluid channel and reservoir networks is accomplished by firing 200 mJ pulses from an UV excimer laser at
M Chevallet et al.
Electrophoresis, 19(11), 1901-1909 (1998-09-18)
Severe quantitative loss of protein is often observed in high-resolution two-dimensional electrophoresis of membrane proteins, while the resolution is usually not affected. To improve the solubility of proteins in this technique, we tested denaturing cocktails containing various detergents and chaotropes.

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