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Merck

45708

Supelco

Zinc dimethyldithiocarbamate

PESTANAL®, analytical standard

Sinónimos:

Zinc dimethyldithiocarbamate, Dimethyldithiocarbamic acid zinc salt, Ziram

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About This Item

Fórmula lineal:
(CH3)2NCSSZnSCSN(CH3)2
Número de CAS:
Peso molecular:
305.82
Beilstein/REAXYS Number:
3707008
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

reaction suitability

reagent type: catalyst
core: zinc

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

mp

248-257 °C (lit.)

application(s)

agriculture
cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

storage temp.

2-8°C

SMILES string

CN(C)C(=S)S[Zn]SC(=S)N(C)C

InChI

1S/2C3H7NS2.Zn/c2*1-4(2)3(5)6;/h2*1-2H3,(H,5,6);/q;;+2/p-2

InChI key

DUBNHZYBDBBJHD-UHFFFAOYSA-L

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General description

Ziram is a fungicide, widely used for the protection of vegetable crops, seed foliage and fruits. It is also employed in rubber industry as an antioxidant and vulcanization accelerator.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Ziram may be used as an analytical reference standard for the quantification of the analyte in environmental samples, grains, and vegetable samples using different analytical techniques.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3

target_organs

Liver,Blood, Respiratory system

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Certificados de análisis (COA)

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Spectrophotometric determination of ziram (dithiocarbamate fungicide) by thiocyanate and rhodamine 6G method
Mathew L, et al.
Talanta, 42(1), 41-43 (1995)
Determination of ziram in vegetable samples by square wave voltammetry
Qui P, et al.
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 19(11), 1337-1340 (2008)
Q Li et al.
International journal of immunopathology and pharmacology, 25(4), 883-891 (2013-01-10)
We previously found that ziram, a dithiocarbamate fungicide, significantly inhibited natural killer (NK) activity in a dose-dependent manner. To explore the mechanism of this inhibition, we investigated ziram-induced apoptosis in human NK cells. Human NK-92MI cells were treated with ziram
Direct detection of Ziram by liquid chromatography/atmospheric pressure chemical ionization mass spectrometry.
H Moriwaki et al.
Rapid communications in mass spectrometry : RCM, 15(23), 2374-2376 (2001-12-18)
Zisis Vryzas et al.
Journal of agricultural and food chemistry, 50(8), 2220-2226 (2002-04-04)
A simple and rapid method is presented for the analysis of residues of ethylenebis(dithiocarbamate) (maneb, zineb, and mancozeb) and N,N-dimethyldithiocarbamate (thiram and ziram) fungicides in dry tobacco leaves and peaches. Residues are extracted and hydrolyzed to CS(2) in a single

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