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284513

Sigma-Aldrich

Chlorobenzene

Chlorobenzene
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anhydrous, 99.8%

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About This Item

Fórmula empírica (notación de Hill):
C6H5Cl
Número de CAS:
108-90-7
Peso molecular:
112.56
Beilstein:
605632
Número CE:
203-628-5
Número MDL:
MFCD00000530
Código UNSPSC:
12352101
ID de la sustancia en PubChem:
57648304
NACRES:
NA.21
grado:
anhydrous
Ensayo:
99.8%
bp:
132 °C (lit.)
presión de vapor:
11.8 mmHg ( 25 °C)
En este momento no podemos mostrarle ni los precios ni la disponibilidad

grado

anhydrous

Nivel de calidad

100

densidad de vapor

3.86 (vs air)

presión de vapor

11.8 mmHg ( 25 °C)

Ensayo

99.8%

Formulario

liquid

temp. de autoignición

1178 °F

lim. expl.

7.1 %

impurezas

<0.005% water

residuo de evap.

<0.0005%

índice de refracción

n20/D 1.524 (lit.)

bp

132 °C (lit.)

mp

−45 °C (lit.)

densidad

1.106 g/mL at 25 °C (lit.)

cadena SMILES

Clc1ccccc1

InChI

1S/C6H5Cl/c7-6-4-2-1-3-5-6/h1-5H

Clave InChI

MVPPADPHJFYWMZ-UHFFFAOYSA-N

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Aplicación

Chlorobenzene may be used in the arylation of 2-isobutylthiazole in the presence of palladium (II) acetate-butyldi-1-adamantylphosphine to form 5-phenyl-2-isobutylthiazole.[1] It may also be used as a solvent for the synthesis of rhodium II tetrakis(triphenylacetate) dimer, an efficient rhodium catalyst for nitrene C-H insertion reactions.[2]

Otras notas

The article number 284513-6X1L will be discontinued. Please order the single bottle 284513-1L which is physically identical with the same exact specifications.

Producto relacionado

Referencia del producto
Descripción
Precios

Palabra de señalización

Warning

Frases de peligro

H226,H315,H332,H411

Clasificaciones de peligro

Acute Tox. 4 Inhalation - Aquatic Chronic 2 - Flam. Liq. 3 - Skin Irrit. 2

Código de clase de almacenamiento

3 - Flammable liquids

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

80.6 °F

Punto de inflamabilidad (°C)

27 °C

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number
SDBB2434
SHBS3725
SHBR6876
STBL4171
SHBS0295

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Palladium (II) acetate-butyldi-1-adamantylphosphine catalyzed arylation of electron-rich heterocycles. preparation of 5-phenyl-2-isobutylthiazole.
Organic Syntheses, 89, 105-105 (2009)
Preparation of 4-spirocyclohexyloxazolidinone by C-H bond nitrene insertion
Huard K and Lebel H
Organic Syntheses, 86, 59-59 (2009)
K. Huard and H. Lebel,
Organic Syntheses, 86, 59-69 (2009)
Efficient recyclable organic solar cells on cellulose nanocrystal substrates with a conducting polymer top electrode deposited by film-transfer lamination.
Zhou Y, et al.
Organic Electronics, 15(3), 661-666 (2014)
Catalysts based on pillared clays for the oxidation of chlorobenzene.
Aznarez A, et al.
Catalysis Today, 246, 15-27 (2015)
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Questions

1–3 of 3 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. Hi, I have one question related to chlorobenzene solvent. What is the percentage of oxygen contains in this solvent? Best regrads Suraj

    1 answer

    1. There are no oxygen molecules present in this compound. This product is packaged in a Sure/Seal™ bottle which was developed to protect our growing line of air-sensitive reagents from oxygen and moisture. For more information about the Sure/Seal™ system, check the following link: https://www.sigmaaldrich.com/technical-documents/technical-article/chemistry-and-synthesis/organic-reaction-toolbox/sureseal

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