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Merck

T25305

Sigma-Aldrich

Tetraphenylarsonium(V) chloride hydrate

97%

Sinónimos:

Phenylarsonium chloride, Tetraphenylarsenic chloride

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About This Item

Fórmula lineal:
(C6H5)4As(Cl) · xH2O
Número de CAS:
Peso molecular:
418.79 (anhydrous basis)
Beilstein/REAXYS Number:
3580063
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

assay

97%

reaction suitability

core: arsenic
reagent type: catalyst

mp

258-260 °C (lit.)

SMILES string

O.[Cl-].c1ccc(cc1)[As+](c2ccccc2)(c3ccccc3)c4ccccc4

InChI

1S/C24H20As.ClH.H2O/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;;/h1-20H;1H;1H2/q+1;;/p-1

InChI key

NGDWSDTZKCSLRK-UHFFFAOYSA-M

Application

Cation exchange reagent. Used to prepare arsonium amide, oxime, and carbohydrate derivatives.

pictograms

Skull and crossbonesEnvironment

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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P Gros et al.
Biochemistry, 31(7), 1992-1998 (1992-02-25)
The possibility that simple lipophilic cations such as tetraphenylphosphonium (TPA+), triphenylmethylphosphonium (TPMP+), and diphenyldimethylphosphonium (DDP+) are substrates for the multidrug-resistance transport protein, P-glycoprotein, was tested. Hamster cells transfected with and overexpressing mouse mdr1 or mouse mdr3 exhibit high levels of
E Bibi et al.
Proceedings of the National Academy of Sciences of the United States of America, 90(19), 9209-9213 (1993-10-01)
We describe functional expression of the mouse multidrug-resistance protein (P-glycoprotein; P-gp) in an Escherichia coli mutant defective in the outer membrane protease ompT. Heterologously expressed mdr1 appears as an unglycosylated species with an apparent molecular mass of 140 kDa in
D Wolff et al.
Biochimica et biophysica acta, 688(1), 138-144 (1982-05-21)
In order to elucidate the mechanism of action of organochlorine insecticides on the ion transport in biological membranes, we have studied the effect of DDT and its analog DDE on the structural parameters of phosphatidylethanolamine (PE) planar bilayers. DDT and
Journal of the American Chemical Society, 114, 5130-5130 (1992)
K Yoshioka et al.
Experientia, 42(9), 1022-1023 (1986-09-15)
The effect of lipophilic cations such as triphenylmethylphosphonium, tetraphenylphosphonium and tetraphenylarsonium in addition to dibenzyldimethylammonium on thiamine transport in isolated rat hepatocytes was studied. Lipophilic cations at the concentration 10 microM almost completely inhibited thiamine uptake. Kinetic studies showed that

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