682322

(R)-N-Diphenylphosphino-N-methyl-[(S)-2-diphenylphosphino)ferrocenyl]ethylamine

≥96%

• Sinónimos: (1R)-1-(Diphenylphosphino)-2-[(1R)-1-[(diphenylphosphino)methylamino]ethyl]ferrocene, (R)-Methyl-BoPhoz
• Fórmula empírica (notación de Hill): C₃₇H₃₅FeNP₂
• Número de CAS: 406680-94-2
• Peso molecular: 611.47
• MDL number: MFCD05865220
• UNSPSC Code: 12352005
• PubChem Substance ID: 329760488
• NACRES: NA.22

Propiedades

• assay: ≥96%
• form: solid
• mp: 108.7-113.6 °C
• SMILES string: [Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)N(C)P(c5ccccc5)c6ccccc6
• InChI: 1S/C32H30NP2.C5H5.Fe/c1-26(33(2)35(29-20-11-5-12-21-29)30-22-13-6-14-23-30)31-24-15-25-32(31)34(27-16-7-3-8-17-27)28-18-9-4-10-19-28;1-2-4-5-3-1;/h3-26H,1-2H3;1-5H;/t26-;;/m1../s1
• InChI key: ZIAZHUWEJYUGEO-FBHGDYMESA-N

Descripción

Application

(R)-N-Methyl-N-diphenylphosphino-1-[(S)-2-diphenylphosphino)ferrocenyl]ethylamine-rhodium complex can efficiently catalyze the asymmetric hydrogenation of 2-tert-butoxycarbonylamino-3-cyclopropylacrylic acid benzyl ester to form (S)-2-tert-butoxycarbonylamino-3-cyclopropylpropionic acid benzyl ester.

Efficient ligand for asymmetric hydrogenation

Legal Information

Sold in collaboration with Johnson Matthey Catalyst for research purposes only. US6590115 and any patents arising therefrom apply.

Información de seguridad

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable