![[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(benzylidene)bis(3-bromopyridine)ruthenium(II)](/deepweb/assets/sigmaaldrich/product/structures/261/898/e64eea4e-5a09-4c7d-b400-c43b3517de2a/640/e64eea4e-5a09-4c7d-b400-c43b3517de2a.png)
![[1,3-Bis(2-methylphenyl)-2-imidazolidinylidene]dichloro(2-isopropoxyphenylmethylene)ruthenium(II) Umicore](/deepweb/assets/sigmaaldrich/product/structures/125/321/1d5e70e5-7e2a-43c7-970c-5f9d4182f8e3/640/1d5e70e5-7e2a-43c7-970c-5f9d4182f8e3.png)
![[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(3-methyl-2-butenylidene)(tricyclohexylphosphine)ruthenium(II) Umicore](/deepweb/assets/sigmaaldrich/product/structures/347/315/47b10e48-a567-4d6f-aecf-0ee8785657a5/640/47b10e48-a567-4d6f-aecf-0ee8785657a5.png)
![2,6-Diisopropylphenylimido-neophylidene[(S)-(−)-BIPHEN]molybdenum(VI) ringclosing metathesis catalyst, ≥95.0% (C)](/deepweb/assets/sigmaaldrich/product/structures/312/745/96ea840b-77a7-427a-9db5-fa08b3ffd45e/640/96ea840b-77a7-427a-9db5-fa08b3ffd45e.png)
![Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][[5-[(dimethylamino)sulfonyl]-2-(1-methylethoxy-O)phenyl]methylene-C]ruthenium(II)](/deepweb/assets/sigmaaldrich/product/structures/179/573/f48a2a1e-cf09-4151-8b78-2bab614efd5c/640/f48a2a1e-cf09-4151-8b78-2bab614efd5c.png)
If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
569747
Catalizador Grubbs® M204
Umicore
Sinónimos:
(1,3-Bis(2,4,6-trimetilfenil)-2-imidazolidinilideno)dicloro(fenilmetileno)(triciclohexilfosfina)rutenio, Bencilideno[1,3-bis(2,4,6-trimetilfenil)-2-imidazolidinilideno]dicloro(triciclohexilfosfina)rutenio, Catalizador Grubbs® 2ª Generación, Catalizador Grubbs® M2a (C848), Dicloro[1,3-bis(2,4,6-trimetilfenil)-2-imidazolidinilideno](bencilideno)(triciclohexilfosfina)rutenio(II)
About This Item
Productos recomendados
Nivel de calidad
Formulario
solid
idoneidad de la reacción
core: ruthenium
reagent type: catalyst
reaction type: Ring-Opening Polymerization
mp
143.5-148.5 °C
temp. de almacenamiento
2-8°C
cadena SMILES
CC1=CC(C)=CC(C)=C1N2CCN(C3=C(C)C=C(C)C=C3C)C2=[Ru](Cl)(Cl)=CC4=CC=CC=C4.P(C5CCCCC5)(C6CCCCC6)C7CCCCC7
InChI
1S/C21H26N2.C18H33P.C7H6.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h9-12H,7-8H2,1-6H3;16-18H,1-15H2;1-6H;2*1H;/q;;;;;+2/p-2
Clave InChI
FCDPQMAOJARMTG-UHFFFAOYSA-L
Aplicación
También puede utilizarse como catalizador:
- Para sintetizar cumarinas a partir de compuestos fenólicos a través de RCM.[1]
- Para escindir los (E)-alilo vic-dioles secundarios en aldehídos.[6]
Conozca más acerca de nuestros catalizadores de metátesis
Otras notas
Información legal
Licencia de producto
Este producto, su fabricación o su utilización, están sujetos a una o más patentes de los Estados Unidos publicadas o pendientes (o equivalentes extranjeras) propiedad de o controladas por Umicore PMC. La adquisición de este producto a Umicore PMC. a través de Sigma-Aldrich, sus filiales o sus distribuidores autorizados aporta al comprador una licencia limitada, de una vez, no exclusiva, no transferible y no asignable. La utilización de este producto por el comprador puede infringir patentes propiedad de o controladas por terceras partes. Es responsabilidad exclusiva del comprador asegurar que su utilización del producto no infringe los derechos de patente de terceras partes ni excede el alcance de la licencia aquí otorgada.
Para cualquier otra información sobre el producto, consulte a su contacto local de Umicore PMC en http://www.pmc.umicore.com
Producto relacionado
Palabra de señalización
Warning
Frases de peligro
Consejos de prudencia
Clasificaciones de peligro
Flam. Sol. 2
Código de clase de almacenamiento
4.1B - Flammable solid hazardous materials
Clase de riesgo para el agua (WGK)
WGK 3
Punto de inflamabilidad (°F)
Not applicable
Punto de inflamabilidad (°C)
Not applicable
Equipo de protección personal
Eyeshields, Gloves, type N95 (US)
Elija entre una de las versiones más recientes:
Certificados de análisis (COA)
¿No ve la versión correcta?
Si necesita una versión concreta, puede buscar un certificado específico por el número de lote.
¿Ya tiene este producto?
Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.
Los clientes también vieron
Artículos
Learn tips and tricks for how to properly use inhibitors including how to select the right inhibitor and how to plan experiments with inhibitors.
Learn tips and tricks for how to properly use inhibitors including how to select the right inhibitor and how to plan experiments with inhibitors.
Learn tips and tricks for how to properly use inhibitors including how to select the right inhibitor and how to plan experiments with inhibitors.
Learn tips and tricks for how to properly use inhibitors including how to select the right inhibitor and how to plan experiments with inhibitors.
Protocolos
TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.
TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.
TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.
TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.
Contenido relacionado
Research focuses on ruthenium alkylidene complexes for versatile olefin metatheses catalysis in the Grubbs group.
Research focuses on ruthenium alkylidene complexes for versatile olefin metatheses catalysis in the Grubbs group.
-
How can I determine the shelf life / expiration / retest date of this product?
1 answer-
Helpful?
-
-
How is shipping temperature determined? And how is it related to the product storage temperature?
1 answer-
Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
Helpful?
-
-
What benefits does Product 569747, Grubbs Catalyst, 2nd Generation, have over other olefin metathesis catalysts?
1 answer-
Grubbs' Catalysts are extraordinarily versatile. They tolerate other functional groups in the alkene and are compatible with a wide range of solvents.
Helpful?
-
-
Is it necessary to handle Product 569747, Grubbs Catalyst, 2nd Generation, under inert atmosphere?
1 answer-
The Grubbs Catalyst is air sensitive. Therefore, we do recommend to handle and store under nitrogen atmosphere.
Helpful?
-
-
What types of reactions is Product 569747, Grubbs Catalyst, 2nd Generation, used in?
1 answer-
It is often used in organic synthesis to achieve olefin cross-metathesis, ring-opening metathesis polymerization (ROMP), and ring-closing metathesis.
Helpful?
-
-
What is the Department of Transportation shipping information for this product?
1 answer-
Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
Helpful?
-
-
What is the difference between the First and Second Generation Grubbs Catalyst?
1 answer-
The Second Generation Catalyst has the same uses in organic synthesis as the First Generation Catalyst, but it has a higher activity.
Helpful?
-
-
How do I order larger quantities of Product 569747, Grubbs Catalyst, 2nd Generation?
1 answer-
Commercial quantities are available directly from Materia. Their phone number is 626-584-8400, or their e-mail address is [email protected].
Helpful?
-
Active Filters
Nuestro equipo de científicos tiene experiencia en todas las áreas de investigación: Ciencias de la vida, Ciencia de los materiales, Síntesis química, Cromatografía, Analítica y muchas otras.
Póngase en contacto con el Servicio técnico
