392847

4,5-Dimethoxy-2-nitrobenzyl alcohol

98%

• Sinónimos: 6-Nitroveratryl alcohol
• Fórmula lineal: O₂NC₆H₂(OCH₃)₂CH₂OH
• Número de CAS: 1016-58-6
• Peso molecular: 213.19
• Beilstein: 1880093
• Número CE: 213-806-4
• Número MDL: MFCD00014701
• Código UNSPSC: 12352100
• ID de la sustancia en PubChem: 24864489
• NACRES: NA.22

Propiedades

• Ensayo: 98%
• mp: 145-148 °C (lit.)
• grupo funcional: hydroxyl; nitro
• cadena SMILES: COc1cc(CO)c(cc1OC)[N+]([O-])=O
• InChI: 1S/C9H11NO5/c1-14-8-3-6(5-11)7(10(12)13)4-9(8)15-2/h3-4,11H,5H2,1-2H3
• Clave InChI: WBSCOJBVYHQOFB-UHFFFAOYSA-N

Descripción

Descripción general

4,5-Dimethoxy-2-nitrobenzyl alcohol (6-Nitroveratryl Alcohol) is 2-nitrobenzyl alcohol derivative. It has been reported to be one of the oxidation products of veratryl (3,4-dimethoxybenzyl) alcohol by lignin peroxidase (isolated from Phanerochaete chrysosporium).

Aplicación

4,5-Dimethoxy-2-nitrobenzyl alcohol (6-nitroveratryl alcohol) is suitable reagent used in the synthesis of 4,5-dimethoxy-2-nitrobenzyl methacrylate, a photolabile monomer and 2-(4-((4-(4,5-dimethoxy-2-nitrobenzyloxy)phenyl)cyclohexylidene)methyl)phenoxy)-N,N-dimethylethanamine, a caged cyclofen-OH ligand.

It may be used in the synthesis of the following:

• 1-[[(chlorocarbonyl)oxy]methyl]-4,5-dimethoxy-2-nitrobenzene
• bis(4,5-dimethoxy-2-nitrophenyl)ethylene glycol, a photolabile protecting group
• optically-sensitive monomer
• nitroveratryl (NV) protected α-hydroxyacetic acid (αG) (NV-αG-OH), required in the preparation of nitroveratryl (NV) protected cyanomethyl (CM) ester of α-hydroxyacetic acid (αG) (NV-αG-CM)
• 4,5-dimethoxy-2-nitrobenzyl p-nitro-phenylcarbonate
• 6-nitroveratryloxycarbonyl chloride (NVOCCl), a reagent used in the protection of amino function in amino sugars

Información de seguridad

• Código de clase de almacenamiento: 11 - Combustible Solids
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): Not applicable
• Punto de inflamabilidad (°C): Not applicable
• Equipo de protección personal: Eyeshields, Gloves, type N95 (US)