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Merck

327182

Sigma-Aldrich

tert-Butyl acrylate

contains 10-20 ppm monomethyl ether hydroquinone as inhibitor, 98%

Sinónimos:

t-Butyl acrylate

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About This Item

Fórmula lineal:
CH2=CHCOOC(CH3)3
Número de CAS:
Peso molecular:
128.17
Beilstein/REAXYS Number:
1742329
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

assay

98%

form

liquid

contains

10-20 ppm monomethyl ether hydroquinone as inhibitor

refractive index

n20/D 1.410 (lit.)

bp

61-63 °C/60 mmHg (lit.)

density

0.875 g/mL at 25 °C (lit.)

SMILES string

CC(C)(C)OC(=O)C=C

InChI

1S/C7H12O2/c1-5-6(8)9-7(2,3)4/h5H,1H2,2-4H3

InChI key

ISXSCDLOGDJUNJ-UHFFFAOYSA-N

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General description

tert-Butyl acrylate is an organic chemical compound that can be used as a monomer for the preparation of various types of polymers with desirable characteristics. It can undergo free-radical polymerization, which is a common method used to produce polymeric materials. Additionally, tert-butyl acrylate polymers can be copolymerized with other monomers to modify their properties. The versatility of tert-butyl acrylate makes it suitable for a wide range of applications, including coatings, adhesives, sealants, elastomers, and specialty films.

Application

tert-Butyl acrylate is a monomer used to produce poly(tert-butyl acrylate) (PtBA) polymers and copolymers, and poly(acrylic acid) polyelectrolyte brushes. It undergoes radiation polymerization to form TBA-gels for radio-fluorogenic dose imaging applications. The monomer can be used to synthesize Poly(t-butyl acrylate). It may be used as a reactive diluent in a study.

tert-Butyl acrylate can also be used as:
  • A building block in the synthesis of asymmetric membranes, which are potentially useful in filtration, separation, or gas permeation processes.
  • A monomer in the preparation of a siloxane-incorporated copolymer binder for silicon anodes in lithium-ion batteries.
  • A monomer in the synthesis of poly(tert-butyl acrylate)/carbon nanofiber (CNF) materials through atom transfer radical polymerization (ATRP).

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 2

flash_point_f

62.6 °F - closed cup

flash_point_c

17 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Polymer-gel formation and reformation on irradiation of tertiary-butyl acrylate
Yao T, et al.
Radiation Physics and Chemistry, 97, 147-152 (2014)
Study of the kinetics of step and flash imprint lithography photopolymerization.
Dickey MD, et al.
AIChE Journal, 51(9), 2547-2555 (2005)
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Block Copolymer Synthesis Using a Commercially Available Nitroxide-Mediated Radical Polymerization (NMP) Initiator
Lee NS and Wooley KL
Material Matters, 5(1), 9-9 (2010)

Artículos

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

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