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270865

Sigma-Aldrich

Benzene-1,2-dithiol

96%

Sinónimos:

1,2-Dimercaptobenzene

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About This Item

Fórmula lineal:
C6H4(SH)2
Número de CAS:
17534-15-5
Peso molecular:
142.24
Beilstein/REAXYS Number:
636154
EC Number:
241-530-4
MDL number:
MFCD00004835
UNSPSC Code:
12352100
PubChem Substance ID:
24856407
NACRES:
NA.22

assay

96%
96%

form

liquid

bp

119-120 °C/17 mmHg (lit.)

mp

22-24 °C (lit.)

solubility

water: slightly soluble

density

1.236 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

Sc1ccccc1S

InChI

1S/C6H6S2/c7-5-3-1-2-4-6(5)8/h1-4,7-8H

InChI key

JRNVQLOKVMWBFR-UHFFFAOYSA-N

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General description

The transition metal complexes with benzene-1,2-dithiol as ligand were studied by UV-vis, resonance Raman (rR) and infrared (IR) spectroscopies.

Application

Benzene-1,2-dithiol was used in the preparation of a new type of Schiff base that was required in the synthesis of a new series of copper(II) and zinc(II) complexes.

signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Repr. 2 - Skin Irrit. 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

219.2 °F - closed cup

flash_point_c

104 °C - closed cup

ppe

Eyeshields, Gloves

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N Raman et al.
European journal of medicinal chemistry, 45(11), 5438-5451 (2010-09-25)
A new series of copper(II) and zinc(II) complexes have been designed and synthesized using a new type of Schiff bases derived from the reaction of 3-(3-phenyl-allylidene)-pentane-2,4-dione with para substituted aniline and benzene-1,2-dithiol. Their structures have been established by analytical and
Lee M, et al.
Royal Society of Chemistry Advances, 5, 86402-86406 (2015)
Taras Petrenko et al.
Journal of the American Chemical Society, 128(13), 4422-4436 (2006-03-30)
Transition metal complexes involving the benzene-1,2-dithiol (L(2-)) and Sellmann's 3,5-di-tert-butylbenzene-1,2-dithiol(L(Bu 2-)) ligands have been studied by UV-vis, infrared (IR), and resonance Raman (rR) spectroscopies. Raman spectra were obtained in resonance with the intervalence charge transfer (IVCT) bands in the near-infrared
Ikram Debbarh et al.
Journal of analytical toxicology, 28(1), 41-45 (2004-02-28)
Ethylenebisdithiocarbamate (EBDC) fungicides are the most important class of organic fungicides and exhibit a high degree of carcinogenicity, mutagenicity, and neurotoxicity. For that reason, the safe application of these fungicides in practice requires a convenient method for their determination, applicable
Mengwei Sun et al.
Molecules (Basel, Switzerland), 24(4) (2019-03-01)
Lung cancer is the leading cause of cancer-related death in the Unites States, and approximately 85% of all lung cancers are classified as non-small cell lung cancer (NSCLC), which is extremely difficult to treat and its survival rate is low.
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