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150533

Sigma-Aldrich

Thallium(III) trifluoroacetate

technical grade

Sinónimos:

TTFA, Tris(trifluoroacetato)thallium, Thallic trifluoroacetate, Trifluoroacetic acid thallium(III) salt

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About This Item

Fórmula lineal:
(CF3COO)3Tl
Número de CAS:
23586-53-0
Peso molecular:
543.43
EC Number:
245-761-1
MDL number:
MFCD00000414
UNSPSC Code:
12161600
PubChem Substance ID:
24849042
NACRES:
NA.22

grade

technical grade

Quality Level

100

reaction suitability

core: thallium
reagent type: catalyst

mp

213 °C (dec.) (lit.)

storage temp.

2-8°C

SMILES string

FC(F)(F)C(=O)O[Tl](OC(=O)C(F)(F)F)OC(=O)C(F)(F)F

InChI

1S/3C2HF3O2.Tl/c3*3-2(4,5)1(6)7;/h3*(H,6,7);/q;;;+3/p-3

InChI key

PSHNNUKOUQCMSG-UHFFFAOYSA-K

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Application

Oxidizing agent used in the synthesis of S-substituted cysteine peptides and proteins containing disulfide bonds.

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Taylor, E. C.; Katz, A. H. et al.
Tetrahedron Letters, 26, 5963-5963 (1985)
Tetrahedron, 44, 805-805 (1988)
Pamela R Hall et al.
Antimicrobial agents and chemotherapy, 52(6), 2079-2088 (2008-04-09)
Viral entry into susceptible host cells typically results from multivalent interactions between viral surface proteins and host entry receptors. In the case of Sin Nombre virus (SNV), a New World hantavirus that causes hantavirus cardiopulmonary syndrome, infection involves the interaction
Shenglong Zhu et al.
Nutrition and cancer, 72(4), 696-707 (2019-07-30)
Kudingcha is implicated in alleviating metabolic disorders in traditional Chinese medicine. However, the role of Kudingcha, one of the Ligustrum robustum species, in metabolic regulations and its antitumor activity in triple-negative breast cancer (TNBC) remains to be determined. Two breast
Luis Julià et al.
Magnetic resonance in chemistry : MRC, 49(4), 164-167 (2011-03-26)
Electron paramagnetic resonance (EPR) analysis of neutral and acidic solutions of 2,5-dimethyl-1-phenylpyrrol (1) and meta-, para-, and ortho-bis(2,5-dimethylpyrrol-1-yl)benzenes (4-6) in the presence of Tl(III) trifluoroacetate as oxidant reveals the poor stability of their generated monomeric radical cations which dimerize through
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Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis, and are some of the organic chemist’s most powerful tools for creating novel products. Below is a list of the most commonly used oxidizing and reducing agents currently available in our catalog.

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