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A10507

Sigma-Aldrich

Acetone oxime

98%

Synonym(s):

β-Isonitrosopropane, 2-Propanone oxime, Acetoxime, Dimethyl ketoxime, N-Isopropylidenehydroxylamine, Propanone oxime

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About This Item

Linear Formula:
(CH3)2C=NOH
CAS Number:
127-06-0
Molecular Weight:
73.09
Beilstein:
1560146
EC Number:
204-820-1
MDL number:
MFCD00002118
UNSPSC Code:
12352100
PubChem Substance ID:
24890499
NACRES:
NA.02

Quality Level

200

Assay

98%

form

crystals

bp

135 °C (lit.)

mp

60-63 °C (lit.)

density

0.901 g/mL at 25 °C (lit.)

SMILES string

C\C(C)=N/O

InChI

1S/C3H7NO/c1-3(2)4-5/h5H,1-2H3

InChI key

PXAJQJMDEXJWFB-UHFFFAOYSA-N

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Signal Word

Danger

Hazard Statements

H228,H312,H317,H318,H351

Hazard Classifications

Acute Tox. 4 Dermal - Carc. 2 - Eye Dam. 1 - Flam. Sol. 2 - Skin Sens. 1B

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL3313
BCCK6318
BCCG6807
BCCG3394
BCCF3205

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N Guo et al.
Carcinogenesis, 11(9), 1659-1662 (1990-09-01)
The hepatocarcinogens 2-nitropropane and acetoxime have previously been found to induce a specific and qualitatively identical pattern of base damage in rat liver DNA and RNA, including the induction of increased levels of 8-hydroxyguanine. Because both 2-nitropropane and acetoxime are
A A Caro et al.
Nitric oxide : biology and chemistry, 5(4), 413-424 (2001-08-04)
Ketoximes undergo a cytochrome P450-catalyzed oxidation to nitric oxide and ketones in liver microsomes. In addition, nitric oxide synthase (NOS) can catalyze the oxidative denitration of the >C=N-OH group of amidoximes. The objective of this work was to characterize the
J Torreilles et al.
Biochimie, 65(4-5), 295-298 (1983-04-01)
Preparation of adducts from nicotinamide adenine dinucleotide and a number of oximes is described; these include acetoxime, pyruvatoxime, cyclohexanoxime, cyclopentanoxime. These adducts are closely related to the corresponding NAD-ketone adducts in their spectra properties, but they are stable in acid
S S Mirvish et al.
Cancer letters, 41(2), 211-216 (1988-08-15)
We tested the ability of phenobarbital and two liver carcinogens, acetoxime and 1-nitroso-5,6-dihydrouracil (NDHU), to induce hyperplastic liver nodules (HLN) in MRC-Wistar and Wistar rats, using a system that included a single diethylnitrosamine (DEN) treatment, partial hepatectomy, and administration of
M Rysková et al.
Folia biologica, 43(1), 19-24 (1997-01-01)
The genotoxic effects of N-nitroso-N-methylurea (MNU) and acetone oxime (ACOX) were tested in the Somatic Mutation and Recombination Test (SMART) in Drosophila melanogaster. We have performed the same assay on transgenic flies expressing the human gene encoding a glutathione S-transferase
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