13742
(±)-3-Benzyloxy-1,2-propanediol
≥97.0% (HPLC)
Synonym(s):
(±)-1-Benzylglycerol, (±)-Glycerol 1-benzyl ether
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About This Item
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Quality Level
Assay
≥97.0% (HPLC)
refractive index
n20/D 1.533
density
1.140 g/mL at 20 °C (lit.)
SMILES string
OCC(O)COCc1ccccc1
InChI
1S/C10H14O3/c11-6-10(12)8-13-7-9-4-2-1-3-5-9/h1-5,10-12H,6-8H2
InChI key
LWCIBYRXSHRIAP-UHFFFAOYSA-N
General description
(±)-3-Benzyloxy-1,2-propanediol undergoes enantioseparation by ligand exchange micellar electrokinetic chromatography using borate anion as a central ion.
Application
(±)-3-Benzyloxy-1,2-propanediol was used in capillary electrophoretic enantioseparation of vicinol diols using different β-cyclodextrin derivatives and borate. It was used in the synthesis and immobilization of 2,3-di-O-phytanyl-sn-glycerol-1-tetraethylene glycol-(3-trichloropropyl-silane) ether lipid (DPTTC) and 2,3-di-O-phytanyl-sn-glycerol-1-tetraethylene glycol-(3-chloro-dimethylpropyl-silane) ether lipid(DPTDC).
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Electrophoresis, 26(20), 3884-3889 (2005-09-17)
Three compounds having 1,2-diol structure (1-phenyl-1,2-ethanediol, 3-phenoxy-1,2-propanediol, and 3-benzyloxy-1,2-propanediol) were enantioseparated by ligand exchange MEKC using (5S)-pinanediol (SPD) as a chiral selector and borate anion as a central ion together with SDS. When (S)-1,2-propanediol, (S)-1,2,4-butanetriol, or (S)-3-tert-butylamino-1,2-propanediol were used as
Capillary electrophoretic chiral resolution of vicinal diols by complexation with borate and cyclodextrin: Comparative studies on different cyclodextrin derivatives.
Chirality, 9(2), 153-156 (1997)
Biophysical journal, 89(3), 1780-1788 (2005-08-30)
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