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377341

Sigma-Aldrich

Sodium metatungstate hydrate

powder

Synonym(s):

Sodium polytungstate hydrate

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About This Item

Linear Formula:
3Na2WO4 · 9WO3 · xH2O
CAS Number:
Molecular Weight:
2968.00 (anhydrous basis)
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

form

powder

Quality Level

composition

W, 70%

reaction suitability

core: tungsten
reagent type: catalyst

SMILES string

O.[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O

InChI

1S/6Na.H2O.39O.12W/h;;;;;;1H2;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/q6*+1;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;6*-1;;;;;;;;;;;;

InChI key

YVQUUPJGDSQKML-UHFFFAOYSA-N

Application

Sodium metatungstate hydrate (NaW12O39 XH2O) can be used as a precursor for the preparation of:
  • Tungsten oxide (WO3 x H2O) nanoplates for the electrocatalytic reaction of methanol oxidation.
  • Tungsten carbide (WC) based counter electrodes for dye-sensitized solar cells (DSSCs).

Suitable for sink/swim analysis

Pictograms

Exclamation markCorrosion

Signal Word

Danger

Hazard Statements

Precautionary Statements

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Characterizations of tungsten carbide as a non-Pt counter electrode in dye-sensitized solar cells
Ko A-Ra, et al.
Materials Letters, 65(14), 2220-2223 (2011)
Improved Electrocatalytic Activity of Size-Controlled Single-Crystalline Tungsten Oxide Nanoplates under Visible-Light Illumination
Moon J-S, et al.
International Journal of Electrochemical Science, 8, 6656-6663 (2013)

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