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804177

Sigma-Aldrich

SnAP 3-Spiro-(2-Pyr) M Reagent

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About This Item

Empirical Formula (Hill Notation):
C23H48N2O3Sn
Molecular Weight:
519.35
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

form

liquid

Quality Level

refractive index

n/D 1.489

density

1.122

storage temp.

−20°C

SMILES string

CCCC[Sn](CCCC)(COCC1(CN(C(OC(C)(C)C)=O)CC1)N)CCCC

InChI

1S/C11H21N2O3.3C4H9.Sn/c1-10(2,3)16-9(14)13-6-5-11(12,7-13)8-15-4;3*1-3-4-2;/h4-8,12H2,1-3H3;3*1,3-4H2,2H3;

InChI key

JLZWEXDNLRNRBE-UHFFFAOYSA-N

General description

The product is a substituted SnAP [Sn(tin) amino protocol] reagent. SnAP reagents are air and moisture stable.

Application

SnAP Reagents provide a one-step route, in tandem with various aldehyde substrates, to saturated N-heterocycles. The synthesis of N-heterocycles through SnAP Reagents requires mild reaction conditions, and aldehydes bearing aryl, heteroaryl, glyoxyl, aliphatic, and halogenated groups are well tolerated. This product was introduced in collaboration with the Bode Research Group

Automate your N-heterocycle formation with Synple Automated Synthesis Platform (SYNPLE-SC002)

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Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3


Certificates of Analysis (COA)

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Protocols

SnAP Reagents facilitate synthesis of saturated N-heterocycles for diverse structures.

SnAP Reagents facilitate synthesis of saturated N-heterocycles for diverse structures.

SnAP Reagents facilitate synthesis of saturated N-heterocycles for diverse structures.

SnAP Reagents facilitate synthesis of saturated N-heterocycles for diverse structures.

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