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Key Documents

361844

Sigma-Aldrich

Chlorotris(triphenylphosphine)cobalt(I)

97%

Synonym(s):

CoCl(Ph3P)3

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About This Item

Linear Formula:
[(C6H5)3P]3CoCl
CAS Number:
Molecular Weight:
881.24
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

form

powder

reaction suitability

core: cobalt
reagent type: catalyst

mp

135-139 °C (dec.) (lit.)

SMILES string

Cl[Co].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9

InChI

1S/3C18H15P.ClH.Co/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1

InChI key

RHNBOEDTKLKUEB-UHFFFAOYSA-M

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Application

A stoichiometric reducing agent employed in the radical dimerization of halogenated organic molecules.

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Pictograms

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Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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