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309206

Sigma-Aldrich

Rhodium(III) nitrate solution

~10 % (w/w) (Rh in >5 wt. % HNO3)

Synonym(s):

Aqueous rhodium nitrate, Rhodium trinitrate, Rhodium(3+)trinitrate

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About This Item

Linear Formula:
Rh(NO3)3
Molecular Weight:
288.92
MDL number:
MFCD00011201
UNSPSC Code:
12352302
PubChem Substance ID:
24858717
NACRES:
NA.23

form

liquid

concentration

≥5.0% (NaOH basis (wt% HNO3, titration))
~10 % (w/w) (Rh in >5 wt. % HNO3)

density

1.41 g/mL at 25 °C

SMILES string

[Rh]

InChI

1S/Rh

InChI key

MHOVAHRLVXNVSD-UHFFFAOYSA-N

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Application

  • The saga of rhodium (III) nitrate complexes and their speciation in solution: An integrated experimental and quantum chemical study of rhodium(III) nitrate complexes in solution (SN Vorobyeva et al., 2022).

Signal Word

Danger

Hazard Statements

H272,H290,H314,H331

Hazard Classifications

Acute Tox. 3 Inhalation - Eye Dam. 1 - Met. Corr. 1 - Ox. Liq. 3 - Skin Corr. 1A

Supplementary Hazards

EUH071

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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A new type of intermolecular rhodium(II)-catalyzed [5+3] cycloaddition has been developed. This higher-order cycloaddition between pyridinium zwitterion 1,5-dipole equivalents and enol diazoacetates enables the formation of eight-membered heterocyclic skeletons, which are otherwise difficult to construct. The optimized cycloaddition occurs efficiently under
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