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Sigma-Aldrich

5,10,15,20-Tetrakis(4-trimethylammoniophenyl)porphyrin tetra(p-toluenesulfonate)

Dye content 90 %

Synonym(s):

TTMAPP

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About This Item

Empirical Formula (Hill Notation):
C84H90N8O12S4
CAS Number:
69458-20-4
Molecular Weight:
1531.92
Beilstein:
6378804
MDL number:
MFCD00012023
UNSPSC Code:
12161600
PubChem Substance ID:
24858498
NACRES:
NA.22

form

powder

Quality Level

100

composition

Dye content, 90%

reaction suitability

core: porphyrin
reaction type: Photocatalysis
reagent type: catalyst

SMILES string

Cc1ccc(cc1)S([O-])(=O)=O.Cc2ccc(cc2)S([O-])(=O)=O.Cc3ccc(cc3)S([O-])(=O)=O.Cc4ccc(cc4)S([O-])(=O)=O.C[N+](C)(C)c5ccc(cc5)-c6c7ccc(n7)c(-c8ccc(cc8)[N+](C)(C)C)c9ccc([nH]9)c(-c%10ccc(cc%10)[N+](C)(C)C)c%11ccc(n%11)c(-c%12ccc(cc%12)[N+](C)(C)C)c%13ccc6[nH]%13

InChI

1S/C56H62N8.4C7H8O3S/c1-61(2,3)41-21-13-37(14-22-41)53-45-29-31-47(57-45)54(38-15-23-42(24-16-38)62(4,5)6)49-33-35-51(59-49)56(40-19-27-44(28-20-40)64(10,11)12)52-36-34-50(60-52)55(48-32-30-46(53)58-48)39-17-25-43(26-18-39)63(7,8)9;4*1-6-2-4-7(5-3-6)11(8,9)10/h13-36,57,60H,1-12H3;4*2-5H,1H3,(H,8,9,10)/q+4;;;;/p-4/b53-45-,53-46-,54-47-,54-49-,55-48-,55-50-,56-51-,56-52-;;;;

InChI key

XFCJLTPKCPNBQV-BHYUYDJESA-J

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Application

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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T Makino et al.
Clinica chimica acta; international journal of clinical chemistry, 111(1), 1-8 (1981-03-19)
A colorimetric method is presented for the accurate determination of serum copper in 0.1 ml sized samples, using alpha, beta, gamma, delta-tetrakis(4-N-trimethylaminophenyl)porphine. This new reagent has high sensitivity (epsilon 433nm = 5.1 X 10(5) l.mol--1.cm--1), it is water-soluble and has
Jianhua Liu et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 67(2), 455-459 (2007-01-27)
A kinetic method performed on a flow injection system is described for the determination of ascorbic acid by using its catalytic effect on the complexation reaction of Cu(II) with 5,10,15,20-tetrakis(4-N-trimethyl-aminophenyl)porphyrin. The characteristic spectrum of porphyrin (Soret band), which shows intense
G D Robinson et al.
Journal of nuclear medicine : official publication, Society of Nuclear Medicine, 27(2), 239-242 (1986-02-01)
Indium-111- (111In) labeled tetra (N,N,N-trimethylanilinium) porphyrin (TTAP), tetra (N-methyl-4-pyridyl)porphyrin (TMPyP), and tetra(4-sulfonatophenyl)porphyrin (T4SPP) were synthesized and lymph node uptake was measured in animals after intravenous administration. In rats [111In] TTAP had maximum lymph node to muscle uptake ratios which averaged
T Makino
Clinica chimica acta; international journal of clinical chemistry, 282(1-2), 65-76 (1999-05-26)
A direct colorimetric method is presented for simple and sensitive determination of serum zinc in 0.05-ml samples, using a cationic porphyrin, alpha,beta,gamma,delta-tetrakis(4-N-trimethylaminophenyl) porphine tetratoluenesulfonate salt (ttmapp, epsilon = 41.5 x 10(4) l/mol per cm at 421 nm). 7-Iodo-8-hydroxyquinoline-5-sulfonic acid (Ferron)
Izabela Hanyz et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 1(2), 126-132 (2003-03-28)
We have studied the influence of solvent acidity on the aggregation/protonation behaviour of two charged tetraphenylporphyrins: positively charged tetrakis(N,N,N-trimethylanilinium-4-yl)porphyrin (TAP) and negatively charged tetrakis(4-sulfonatophenyl)porphyrin (TPPS4). Spectroscopic measurements (absorption, fluorescence, excitation and photoacoustic) have been made to follow the radiative and
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