Skip to Content
Merck
All Photos(1)

Documents

211354

Sigma-Aldrich

(R)-(−)-1-(9-Anthryl)-2,2,2-trifluoroethanol

≥98%

Synonym(s):

(R)-(−)-α-(Trifluoromethyl)anthracene-9-methanol, (R)-(−)-2,2,2-Trifluoro-1-(9-anthryl)ethanol

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C16H11F3O
CAS Number:
53531-34-3
Molecular Weight:
276.25
Beilstein:
4695163
EC Number:
258-611-5
MDL number:
MFCD00001260
UNSPSC Code:
12352005
PubChem Substance ID:
24852682
NACRES:
NA.22

Quality Level

100

Assay

≥98%

optical activity

[α]25/D −30°, c = 6.0 in chloroform

optical purity

ee: 98% (HPLC)

mp

132-135 °C (lit.)

SMILES string

O[C@H](c1c2ccccc2cc3ccccc13)C(F)(F)F

InChI

1S/C16H11F3O/c17-16(18,19)15(20)14-12-7-3-1-5-10(12)9-11-6-2-4-8-13(11)14/h1-9,15,20H/t15-/m1/s1

InChI key

ICZHJFWIOPYQCA-OAHLLOKOSA-N

Looking for similar products? Visit Product Comparison Guide

Application

These enantiomerically pure (+)- and (−)-2,2,2-trifluoro-1-(9-anthryl)ethanols have been used for the NMR spectral determination of optical purity (and in some cases, absolute configuration) of a wide variety of sulfoxides, lactones, amines, sulfinate esters, oxaziridines and allenes.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Journal of Chromatography A, 123, 400-400 (1976)
Journal of the American Chemical Society, 98, 1832-1832 (1976)
M J Zhao et al.
Journal of chromatography. B, Biomedical applications, 656(2), 441-446 (1994-06-17)
A relatively rapid, inexpensive, sensitive and stereospecific gas chromatographic-mass spectrometric method was developed for the quantification of S(+) and R(-)-ibuprofen in human plasma. This method uses a commercially available internal standard and has no interference from endogenous substances nor metabolites.
The Journal of Organic Chemistry, 42, 3697-3697 (1977)
Leonid Asnin et al.
Journal of chromatography. A, 1091(1-2), 183-186 (2006-01-06)
The enantioseparation of 2,2,2-trifluoro-1-(9-anthryl)ethanol on silica-bonded quinidine carbamate was examined under linear chromatographic conditions. The significant impact of nonselective adsorption on the retention was demonstrated. The influences of a polar additive in the mobile phase on the retention, the selectivity
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service