P10801
Perinaphthenone
97%
Synonym(s):
1H-Benzonaphthen-1-one, 7-Perinaphthenone, Phenalenone, Phenalone
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About This Item
Empirical Formula (Hill Notation):
C13H8O
CAS Number:
Molecular Weight:
180.20
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
97%
form
powder
mp
153-156 °C (lit.)
SMILES string
O=C1C=Cc2cccc3cccc1c23
InChI
1S/C13H8O/c14-12-8-7-10-4-1-3-9-5-2-6-11(12)13(9)10/h1-8H
InChI key
WWBGWPHHLRSTFI-UHFFFAOYSA-N
Application
Perinaphthenone can be used:
- In the Weitz-Scheffer epoxidation to produce the corresponding epoxides in the presence of gem-dihydroperoxide as the stoichiometric oxidant.
- As a photosensitizer in the photodegradation of tebuconazole.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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William Hidalgo et al.
Journal of agricultural and food chemistry, 57(16), 7417-7421 (2009-07-28)
The levels of native fungitoxic perinaphthenone phytoalexins in susceptible Musa varieties (banana), which are commercially grown in large plantations, are too low to provide plants with long-lasting protection against highly pathogenic fungi. Novel strategies for plant protection are necessary to
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Accounts of chemical research, 39(5), 293-300 (2006-05-17)
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Covering up to the end of August 2013. Phenalenones are members of a unique class of natural polyketides exhibiting diverse biological potential. This is a comprehensive review of 72 phenalenones with diverse structural features originating from fungal sources. Their bioactive
Xiaopeng Chen et al.
Chemical communications (Cambridge, England), 47(9), 2628-2630 (2011-01-15)
Phenalenone derivatives were efficiently constructed from 1,8-diiodonaphthalene and tertiary propynols via a one-pot domino reaction which eventually included Pd-catalyzed Sonogoshira coupling, Pd-catalyzed allylic oxidation and Pd-catalyzed C(sp(2))-H activation. Moreover, the synthesized phenalenone derivative presented a practical application as a fluorescent
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The incorporation of pigments and natural polyphenols into inorganic matrices, resulting in a hybrid material that improves the resistance and chemical stability of the pigments and the antioxidant capacity of the materials, has been of great interest to the pharmaceutical
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