391743

2-Methyl-1-indanone

99%

• Empirical Formula (Hill Notation): C₁₀H₁₀O
• CAS Number: 17496-14-9
• Molecular Weight: 146.19
• MDL number: MFCD00192303
• UNSPSC Code: 12352100
• PubChem Substance ID: 24864399
• NACRES: NA.22

Properties

• Quality Level: 200
• Assay: 99%
• form: liquid
• refractive index: n20/D 1.555 (lit.)
• bp: 93-95 °C/4 mmHg (lit.)
• density: 1.064 g/mL at 25 °C (lit.)
• SMILES string: CC1Cc2ccccc2C1=O
• InChI: 1S/C10H10O/c1-7-6-8-4-2-3-5-9(8)10(7)11/h2-5,7H,6H2,1H3
• InChI key: BEKNOGMQVKBMQN-UHFFFAOYSA-N

Description

General description

2-Methyl-1-indanone, a α-benzocycloalkenone, is a derivative of 1-indanone. Its synthesis has been reported. The enzymatic dynamic kinetic resolution (DKR) of racemic 2-methyl-1-indanone has been studied. The asymmetric α-arylation and hydroxymethylation of 2-methyl-1-indanone has been reported. It participated in the synthesis of 2-methyl-6-carboxyazulene.

Application

2-Methyl-1-indanone may be used as a starting material in the synthesis of β-benzocycloalkenone. It may be used in the synthesis of the following:

• cyclohex-2-en-1-yl 2-methyl-1H-inden-3-yl carbonate
• 2-hydroxy-2-methyl-1-indanone
• O-alkoxycarbonylation of lithium enolates

Safety Information

• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves