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About This Item
Linear Formula:
BrCH2CH2CHBrCOOCH3
CAS Number:
Molecular Weight:
259.92
Beilstein:
1757129
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Assay
≥97.0% (GC)
form
solid
density
1.840 g/mL at 20 °C (lit.)
functional group
bromo
storage temp.
2-8°C
SMILES string
COC(=O)C(Br)CCBr
InChI
1S/C5H8Br2O2/c1-9-5(8)4(7)2-3-6/h4H,2-3H2,1H3
InChI key
DQHIGEQXJBMKKY-UHFFFAOYSA-N
Related Categories
General description
Methyl 2,4-dibromobutyrate reacts with sodium azide in dimethylformamide to yield 2-azido-4-bromobutyrate.
Application
Methyl 2,4-dibromobutyrate was used in the preparation of stereoisomers of azetidine-2-carboxylic amide derivative.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Observations on the chemistry of. alpha.-azido ester. Efficient synthesis of a potently sweet homoserine-dihydrochalcone conjugate.
DuBois GE, et al.
The Journal of Organic Chemistry, 47(7), 1319-1323 (1982)
Synthesis and X-ray analysis of 1-((1S)-phenylethyl)-azetidine-(2R)-piperidinamide.
De Gelder R, et al.
Journal of Chemical Crystallography, 26(9), 639-642 (1996)
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