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232041

Sigma-Aldrich

Cesium hydroxide solution

50 wt. % in H2O, 99.9% trace metals basis

Synonym(s):

Caesium hydroxide

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About This Item

Linear Formula:
CsOH
CAS Number:
Molecular Weight:
149.91
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
Assay:
99.9% trace metals basis
form:
liquid
Pricing and availability is not currently available.

Quality Level

Assay

99.9% trace metals basis

form

liquid

concentration

50 wt. % in H2O

impurities

≤1000.0 ppm Trace Metal Analysis

density

1.72 g/mL at 25 °C

SMILES string

[OH-].[Cs+]

InChI

1S/Cs.H2O/h;1H2/q+1;/p-1

InChI key

HUCVOHYBFXVBRW-UHFFFAOYSA-M

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Application

Cesium hydroxide solution is used to make porous cesium titanosilicates, potential ion-exchange materials for cleanup of radioactive wastes.[1]CsOH impregnated in FAU zeolites enhanced their basic properties without affecting the FAU framework.[2]It can effectively catalyse the condensation of methyl propionate with formaldehyde to yield methyl methacrylate.[3]

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Precautionary Statements

Hazard Classifications

Acute Tox. 4 Oral - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Enhancement of the basic properties in FAU zeolites by impregnation with cesium hydroxide
Romero MD, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 81(1-3), 313-320 (2005)
Behrens, E.A. et al.
Chemistry of Materials, 8, 1236-1236 (1996)
Formation of methyl methacrylate by condensation of methyl propionate with formaldehyde over silica-supported cesium hydroxide catalysts
Ai M
Applied Catalysis A: General, 288(1-2), 211-215 (2005)
Felix Neumaier et al.
The Journal of general physiology, 152(9) (2020-06-20)
Loosely bound Zn2+ ions are increasingly recognized as potential modulators of synaptic plasticity and neuronal excitability under normal and pathophysiological conditions. Cav2.3 voltage-gated Ca2+ channels are among the most sensitive targets of Zn2+ and are therefore likely to be involved
M M V Ramana et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 152, 165-171 (2015-07-25)
In the present work, isopropyl-6-amino-4-(3,5-bis(trifluoromethyl)phenyl)-5-cyano-2-methyl-4H-pyran-3-carboxylate (4H-pyran analog) has been synthesized by a three component reaction catalyzed by CsOH/γ-Al2O3 and characterized. The interaction of 4H-pyran analog with herring sperm DNA (hs DNA) under physiological conditions (phosphate buffer of pH 7.2) was

Articles

Colloidal quantum dots (CQDs) are semiconducting crystals of only a few nanometers (ca. 2–12 nm) coated with ligand/surfactant molecules to help prevent agglomeration.

Questions

1–3 of 3 Questions  
  1. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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  2. How does the storage temperature relate to shipping conditions?

    1 answer
    1. The storage conditions that a Sigma-Aldrich catalog and label recommend for products are deliberately conservative. For many products, long-term storage at low temperatures will increase the time during which they are expected to remain in specification and therefore are labeled accordingly. Where short-term storage, shipping time frame, or exposure to conditions other than those recommended for long-term storage will not affect product quality, Sigma-Aldrich will ship at ambient temperature. The products sensitive to short-term exposure to conditions other than their recommended long-term storage are shipped on wet or dry ice. Ambient temperature shipping helps to control shipping costs for our customers. At any time, our customers can request wet- or dry-ice shipment, but the special handling is at customer expense if our product history indicates that the product is stable for regular shipment.

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  3. What is the molarity of Product 232041, Cesium hydroxide solution?

    1 answer
    1. The molar concentration of Product 232041, Cesium hydroxide solution, is 5.7 M, based on a w/w% concentration of 50%, a density of 1.72 g/mL and a MW of 149.91. (50 g CsOH/100 g solution) X (1720 g solution/L solution) /(149.91 g CsOH/mole) = 5.7 moles/L.

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