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ALD00570

Sigma-Aldrich

1-((4-(Trifluoromethyl)phenyl)sulfonyl)bicyclo[2.1.0]pentane

racemic version, 95%

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About This Item

Empirical Formula (Hill Notation):
C12H11F3O2S
Molecular Weight:
276.27
UNSPSC Code:
12352200
NACRES:
NA.22

Quality Level

100

Assay

95%

form

solid

reaction suitability

reaction type: C-C Bond Formation

Application

The following "spring-loaded" electrophile is a convenient reagent for the installation of cyclopentane to primary and secondary amines. This product is one of several synthetically useful reagents reported by Baran and coworkers for the “any-stage” installation of small, strained ring systems.

Other Notes

Strain-release amination

Strain-Release Heteroatom Functionalization: Development, Scope, and Stereospecificity

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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