902128
(Z)-N′-Cyanopicolinimidamide
Synonym(s):
Weix 2-pyridyl-N-cyanocarboxamidine ligand for nickel catalysis
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About This Item
Empirical Formula (Hill Notation):
C7H6N4
CAS Number:
Molecular Weight:
146.15
MDL number:
UNSPSC Code:
12352111
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form
powder or crystals
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
reagent type: ligand
mp
201-205 °C
Application
This pyridyl carboxamidine ligand has been demonstrated by Daniel Weix′s lab to enable nickel-catalyzed cross-coupling of diverse basic nitrogen heterocycles with primary and secondary alkyl halides.
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Product No.
Description
Pricing
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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Eric C Hansen et al.
The Journal of organic chemistry, 82(14), 7085-7092 (2017-07-07)
Despite their importance, the synthesis of alkylated heterocycles from the cross-coupling of Lewis basic nitrogen heteroaryl halides with alkyl halides remains a challenge. We report here a general solution to this challenge enabled by a new collection of ligands based
Eric C Hansen et al.
Nature chemistry, 8(12), 1126-1130 (2016-11-23)
Ligands are essential for controlling the reactivity and selectivity of reactions catalysed by transition metals. Access to large phosphine ligand libraries has become an essential tool for the application of metal-catalysed reactions industrially, but these existing libraries are not well
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