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275913

Sigma-Aldrich

Tricarbonyl(cyclooctatetraene)iron(II)

98%

Synonym(s):

1,3,5,7-Cyclooctatetraeneiron tricarbonyl, Cyclooctatetraenetricarbonyliron, NSC 167370, NSC 168049

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About This Item

Linear Formula:
C8H8Fe(CO)3
CAS Number:
Molecular Weight:
244.02
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Assay

98%

form

solid

reaction suitability

core: iron
reagent type: catalyst

mp

93-95 °C (lit.)

SMILES string

[Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=CC=CC=C1

InChI

1S/C8H8.3CO.Fe/c1-2-4-6-8-7-5-3-1;3*1-2;/h1-8H;;;;/b2-1-,3-1-,4-2-,5-3-,6-4-,7-5-,8-6-,8-7-;;;;

InChI key

XAOCYVWRKJTXOL-CJNMVQMASA-N

Application

Catalyst for:
  • Light-driven hydrogen generation via reduction of water
  • Growth of multiwalled carbon nanotubes
  • Tandem isomerization-aldol condensation of allylic alcohols
  • Hydrogenation of anthracene and nitrogen heterocycles under water-gas shift conditions

Used:
  • For VPE-growth of iron-doped indium phosphide by metal organic chemical vapor deposition (MOCVD)
  • As sensitizer for isomerization of norbornadiene in solar-energy storage

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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