471313

Tributylamine

≥98.5%

• Synonym(s): Tri-n-butylamine
• Linear Formula: [CH₃(CH₂)₃]₃N
• CAS Number: 102-82-9
• Molecular Weight: 185.35
• Beilstein: 1698872
• EC Number: 203-058-7
• MDL number: MFCD00009431
• UNSPSC Code: 12352100
• PubChem Substance ID: 329757295
• NACRES: NA.21

Properties

• vapor density: 6.38 (vs air)
• Quality Level: 200
• vapor pressure: 0.3 mmHg ( 20 °C); 2.4 mmHg ( 55 °C)
• Assay: ≥98.5%
• form: liquid
• autoignition temp.: 410 °F
• expl. lim.: 6 %
• refractive index: n20/D 1.428 (lit.)
• pH: 10.2 (25 °C, 0.1 g/L)
• bp: 216 °C (lit.)
• mp: −70 °C (lit.)
• density: 0.778 g/mL at 25 °C (lit.)
• SMILES string: CCCCN(CCCC)CCCC
• InChI: 1S/C12H27N/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3
• InChI key: IMFACGCPASFAPR-UHFFFAOYSA-N

Description

General description

Tributylamine (TBA) is a tertiary amine used as strong base anion (SBA) exchange resin. TBA can also be used as a corrosion inhibitor for mild steel in HCl solution. Additionally, it can be used as a base solvent in various organic synthesis.

Application

Tributylamine may be used as:

• An extraction solvent with CHCA (α-cyano-4-hydroxycinnamic acid) for the selective phospholipids (PLs) extraction from EVOO (extra virgin olive oil) and HO (hazelnut oil).
• A hydroxylating agent in the synthesis of spinel nickel ferrites (NiFe₂O₄) nanoparticles (NPs).

Features and Benefits

In various co-precipitation methods, tributylamine is used as a hydroxylating agent instead of NaOH and NH₄OH since it causes a uniform rise in pH which prevents local supersaturation and promotes homogeneous nucleation throughout the solution.

Safety Information

• Pictograms: GHS06
• Signal Word: Danger
• Hazard Statements: H302,H310 + H330,H315
• Precautionary Statements: P260 - P262 - P280 - P301 + P312 - P302 + P352 + P310 - P304 + P340 + P310
• Hazard Classifications: Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 4 Oral - Skin Irrit. 2
• Storage Class Code: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 1
• Flash Point(F): 145.4 °F - closed cup
• Flash Point(C): 63 °C - closed cup