- Synthesis of rhenabenzenes from the reactions of rhenacyclobutadienes with ethoxyethyne.
Synthesis of rhenabenzenes from the reactions of rhenacyclobutadienes with ethoxyethyne.
Chemistry (Weinheim an der Bergstrasse, Germany) (2014-09-16)
Ran Lin, Ka-Ho Lee, Ka Chun Poon, Herman H Y Sung, Ian D Williams, Zhenyang Lin, Guochen Jia
PMID25220667
摘要
Treatment of Na[Re(CO)5 ] with RCCCO2 Et (R=phenyl, naphthalen-1-yl, phenanthren-9-yl and pyren-1-yl) followed by reaction with acetyl chloride and ethanol afforded the rhenacyclobutadienes Re{-C(R)C(CO2 Et)C(OEt)}(CO)4 . Reactions of these rhenacyclobutadienes with HCCOEt produced rhenabenzenes Re{-C(R)C(CO2 Et)C(OEt)CHC(OEt)}(CO)4 . Except for R=Ph, new rhenacyclobutadienes with pendant alkenyl substituents Re{-C(R)C(C(OEt)CH(CO2 Et))C(OEt)}(CO)4 were also isolated from these reactions. The NMR spectroscopic and X-ray structural data, as well as the aromatic stabilization energy (ASE) values suggest that the rhenabenzenes are aromatic, with extensive delocalized π character.
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