跳转至内容
Merck
  • Non-edible babassu oil as a new source for energy production-a feasibility transesterification survey assisted by ultrasound.

Non-edible babassu oil as a new source for energy production-a feasibility transesterification survey assisted by ultrasound.

Ultrasonics sonochemistry (2012-12-05)
Eduardo J M Paiva, Maria Lucia C P da Silva, Jayne C S Barboza, Pedro C de Oliveira, Heizir F de Castro, Domingos S Giordani
摘要

Ethyl esters of babassu oil were synthesized by alkaline catalysis to make the green production of biodiesel feasible with simple methods and available technology. Babassu oil is a transparent, light yellow oil extracted from the seeds of the babassu palm (Orbinya sp), and due to its high saturated fatty acid composition (83%), it is considered a non-inedible oil. Transesterification using ethanol represents a valid alternative to using methanol because of ethanol's lower toxicity and the higher yield on weight compared to methanol. Statistical methodology was applied to optimize the transesterification reaction, which was promoted by ultrasonic waves and mechanical agitation. Nuclear magnetic resonance spectroscopy was used to quantify the conversion attained. Alkaline transesterification assisted by ultrasound produced the best results with respect to reaction time and the phase separation step. The model obtained showed that conversions higher than 97% may be achieved in 10min with correct tuning of the process variables.

材料
货号
品牌
产品描述

Sigma-Aldrich
氢氧化钾, ACS reagent, ≥85%, pellets
Sigma-Aldrich
氢氧化钾, reagent grade, 90%, flakes
Sigma-Aldrich
氢氧化钾 溶液, 45 wt. % in H2O
Sigma-Aldrich
氢氧化钾, semiconductor grade, pellets, 99.99% trace metals basis (Purity excludes sodium content.)
Supelco
氢氧化钾 溶液, volumetric, 8.0 M KOH (8.0N)
Sigma-Aldrich
氢氧化钾, ≥85% KOH basis, pellets, white
Sigma-Aldrich
氢氧化钾, BioXtra, ≥85% KOH basis
Sigma-Aldrich
氢氧化钾, technical, ≥85%, powder
Sigma-Aldrich
氢氧化钾, puriss., meets analytical specification of Ph. Eur., BP, 85-100.5%, pellets
Sigma-Aldrich
氢氧化钾, pellets, reag. Ph. Eur., ≥85%
Sigma-Aldrich
氢氧化钾, puriss. p.a., ≥86% (T), pellets
Supelco
氢氧化钾溶液, 0.1 M KOH in water (0.1N), Eluent concentrate for IC
Supelco
棕榈油, analytical standard
Sigma-Aldrich
氢氧化钾, tested according to Ph. Eur.
Sigma-Aldrich
氢氧化钾, free-flowing, Redi-Dri, ACS reagent, ≥85%, pellets