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Merck

C6696

Sigma-Aldrich

头孢菌素 来源于Cercospora hayii

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About This Item

经验公式(希尔记法):
C29H26O10
CAS号:
分子量:
534.51
MDL號碼:
分類程式碼代碼:
51102829
PubChem物質ID:
NACRES:
NA.85

形狀

solid

品質等級

溶解度

chloroform: 9.80- 10.20 mg/mL, clear, red to red-brown

抗生素活性譜

Gram-positive bacteria

作用方式

cell membrane | interferes

儲存溫度

2-8°C

SMILES 字串

COC1=C(CC(C)O)c2c3c(CC(C)O)c(OC)c(O)c4C(=O)C=C5OCOc6cc(O)c(C1=O)c2c6c5c34

InChI

1S/C29H26O10/c1-10(30)5-12-18-19-13(6-11(2)31)29(37-4)27(35)21-15(33)8-17-23(25(19)21)22-16(38-9-39-17)7-14(32)20(24(18)22)26(34)28(12)36-3/h7-8,10-11,30-32,35H,5-6,9H2,1-4H3

InChI 密鑰

JWFLIMIGORGZMQ-UHFFFAOYSA-N

應用

尾孢菌素(C29H26O10)是一种从香蕉病原体培养物中分离出来的红色色素。它已被用于研究野油菜黄单胞菌百日菊致病变种(Bacterium Xanthomonas campestris pv. Zinniae )等物种的毒素生物降解

生化/生理作用

头孢菌素是一种聚酮化合物植物毒素,可以被光激活,并在激活状态下与氧气反应生成有毒氧物种,例如单线态氧(O2)和超氧化物(O2-)。活性氧的产生导致植物细胞膜中脂质的过氧化。
据报道,光诱导的聚酮化合物植物毒素在光催化下会产生单线态氧。

其他說明

保存于密闭容器内,置于干燥通风处。

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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J D Williamson et al.
Trends in microbiology, 1(6), 239-245 (1993-09-01)
Antioxidant defense systems are a prominent element in plant responses to environmental stress. Activated oxygen species have themselves been implicated as both a part of the plant's defense against pathogen attack as well as the phytotoxic component of photosensitizing fungal
Julia Knöckel et al.
The Biochemical journal, 443(2), 397-405 (2012-01-17)
The malaria parasite Plasmodium falciparum is able to synthesize de novo PLP (pyridoxal 5'-phosphate), the active form of vitamin B6. In the present study, we have shown that the de novo synthesized PLP is used by the parasite to detoxify
Maricela Martínez Jiménez et al.
Mycopathologia, 167(4), 203-208 (2008-10-22)
An evaluation of the potential hazards associated with mutagenicity and acute toxicity of a mycoherbicide formulation based on the fungal pathogen Cercospora piaropi was performed. Neither the mycoherbicide nor any of its components were mutagenic to Salmonella typhimurium TA98 and
Adam G Newman et al.
Chemical communications (Cambridge, England), 48(96), 11772-11774 (2012-10-31)
The polyketide synthase CTB1 is demonstrated to catalyze pyrone formation thereby expanding the known biosynthetic repertoire of thioesterase domains in iterative, non-reducing polyketide synthases.
B H Bluhm et al.
Fungal genetics and biology : FG & B, 45(10), 1364-1372 (2008-08-07)
DNA photolyases harvest light energy to repair genomic lesions induced by UV irradiation, whereas cryptochromes, presumptive descendants of 6-4 DNA photolyases, have evolved in plants and animals as blue-light photoreceptors that function exclusively in signal transduction. Orthologs of 6-4 photolyases

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