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Merck

398063

Sigma-Aldrich

重铬酸钠 二水合物

ACS reagent, ≥99.5%

别名:

红矾钠

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About This Item

线性分子式:
Na2Cr2O7 · 2H2O
CAS号:
分子量:
298.00
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.21

等級

ACS reagent

品質等級

化驗

≥99.5%

形狀

crystals

反應適用性

reagent type: oxidant

雜質

≤0.005% NH4OH ppt.
≤0.005% insolubles

pH值

3.5 (20 °C, 100 g/L)

mp

91 °C (lit.)

負離子痕跡

chloride (Cl-): ≤0.005%
sulfate (SO42-): ≤0.01%

正離子痕跡

Al: ≤0.002%
Ca: ≤0.003%

SMILES 字串

O.O.[Na+].[Na+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O

InChI

1S/2Cr.2Na.2H2O.7O/h;;;;2*1H2;;;;;;;/q;;2*+1;;;;;;;;2*-1

InChI 密鑰

JYDRNIYTFCBIFC-UHFFFAOYSA-N

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一般說明

Sodium dichromate dehydrate (SDD), a hexavalent chromium compound is commonly used as an oxidizing agent. Chromium (VI) compounds are genotoxic and group 1 IARC (International Agency for Research on Cancer) carcinogen. SDD is one of the common contaminants found in drinking water. Its toxic effects and carcinogenicity has been studied.

應用

Sodium dichromate dehydrate may be used in preparing Jones reagent which is employed for oxidation reactions. It may be used in the oxidation of arylalkanes.

訊號詞

Danger

危險分類

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Muta. 1B - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 1 Inhalation

儲存類別代碼

5.1B - Oxidizing hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Shaken not stirred; oxidation of alcohols with sodium dichromate.
Lou JD, et al.
Tetrahedron Letters, 47(3), 311-313 (2006)
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Chromium Oxidations in Organic Chemistry, 29-32G-29-32G (2012)
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New. J. Chem., 39(5), 4115-4127 (2015)
A chronic oral reference dose for hexavalent chromium-induced intestinal cancer.
Thompson CM, et al.
Journal of Applied Toxicology, 34(5), 525-536 (2014)
Lack of genotoxic effects in hematopoietic and gastrointestinal cells of mice receiving chromium (VI) with the drinking water.
De Flora S, et al.
Mutation Research, Reviews in Mutation Research, 659(1), 60-67 (2008)

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